화학공학소재연구정보센터
Macromolecules, Vol.46, No.11, 4575-4579, 2013
Highly Elastic Supramolecular Hydrogels Using Host-Guest Inclusion Complexes with Cyclodextrins
Supramolecular hydrogels, which are cross-linked via host guest interactions, show high-performance physical properties, such as elasticity and toughness. Herein we prepare a supramolecular hydrogel without chemical crosslinker. The supramolecular hydrogel was prepared by polymerization of the inclusion complexes between beta-cyclodextrin acrylamide and adamantane acrylamide monomers. The beta-cyclodextrin adamantane gel (beta CD Ad gel) shows a high stretching property (990%). The initial strain (0%) is restored in several minutes for a beta CD Ad gel stretched to 180% of the initial strain without altering the physical history. However, chemically cross-linked poly(acrylamide) does not show the reversible stretching property. These results indicate that host guest interaction inside the supramolecular hydrogel plays an important role in the shape recovery properties.