소디움알파술폰 고급지방산 모노글리세리드의 세정성

노윤찬; 이승렬; 윤영균; 남기대

Journal of the Korean Industrial and Engineering Chemistry, Vol.5, No.5, 795-800, October, 1994

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소디움알파술폰 고급지방산 모노글리세리드의 세정성

Detergency Performance of Sodium Monoglycerol α-Sulfonated Alkanonates

노윤찬, 이승렬, 윤영균, 남기대

초록

새로운 기능성을 갖는 sodium monoglycerol α-sulfonated alkanonate류에서 소수성 부분의 알킬기의 탄소수에 따른 세정력을 비교한 결과 C₁₆>C₁₈>C₁₄>C₁₂의 순으로 나타났고, 이들 중 세정력이 가장 우수한 sodium monoglycerol α-sulfonated hexadecanonate는 무공해 세정제로서 기대성이 있는바 현재 봉업적으로 대량 사용하고 있는 sodium α-sulfonated alkanoic acid methyl ester와 sodium alkyl benzene sulfonate를 상대 비교한 결과, 보다 우수한 세정력을 나타내며 공업적 응용성에 기대성이 크다.

The detergencles of these new functional anionic surfactants, sodium monoglycerol α-sulfonated alkanoates, were investigated and compared with those of two commercial surfactants, that is, sodium α-sulfonated alkanoic acid methyl ester and sodium alkyl benzene sulfonate. According to the variation of the hydrophobic alkyl chain length, the order of detergency was shown to be C₁₆>C₁₈>C₁₄>C₁₂. From the comparision experiment for the detergency and the various fundamental properties of two other surfactants, it was found that sodium monoglycerol α-sulfonated hexadecanonate has the most outstanding characteristics of detergency. Possibly this result shows light on its industrial application as a nonpolluting detergent.

[References]

남기대, "계면활성제(1)-기초적 물성-," 193, 수서원 (1991)
Schwartz AM, J. Am. Oil Chem. Soc., 48, 566 (1971)
GaleCutler W, Kissa E, "Detergency Theory and Technology," 493, Marcel Dekker, Inc., New York (1972)
Samrearing Kriengprathana, World Conference on Oleochemical, AOCS (1990)
Ahn H, 3rd Chemical Week Asia/Paciffic Conference (1993)
윤영균, 공학박사 학위논문, 충북대학교, 14 ~ 15 (1994)
한국공업규격: 의류용 합성세제, KS M 2716 (1980)
Kubelka P, Z. Tech. Phisik, 12, 593 (1931)

[Referenced By]

[1] 남기대, "계면활성제(1)-기초적 물성-," 193, 수서원 (1991)

[2] Schwartz AM, J. Am. Oil Chem. Soc., 48, 566 (1971)

[3] GaleCutler W, Kissa E, "Detergency Theory and Technology," 493, Marcel Dekker, Inc., New York (1972)

[4] Samrearing Kriengprathana, World Conference on Oleochemical, AOCS (1990)

[5] Ahn H, 3rd Chemical Week Asia/Paciffic Conference (1993)

[6] 윤영균, 공학박사 학위논문, 충북대학교, 14 ~ 15 (1994)

[7] 한국공업규격: 의류용 합성세제, KS M 2716 (1980)

[8] Kubelka P, Z. Tech. Phisik, 12, 593 (1931)