ABS/PMMA 블렌드에 미치는 고무형태와 카본블랙 첨가에 따른 영향

최치훈; 이수민; 윤이근; 손경호; 김병규

Journal of the Korean Industrial and Engineering Chemistry, Vol.5, No.6, 935-942, December, 1994

Export Citation

ABS/PMMA 블렌드에 미치는 고무형태와 카본블랙 첨가에 따른 영향

Effect of Type of Rubber and Carbon Black Addition on ABS/PMMA Blends

최치훈, 이수민, 윤이근, 손경호, 김병규

초록

두 가지 종류의 고무로부터 ABS를 제조한 후, 각 ABS를 PMMA와 블렌딩하여 블렌드의 몰폴로지, 기계적 성질 및 용융물성을 검토하였다. 또한 블렌드에 카본블랙을 첨가하여 카본블랙의 분산형태 및 블렌드 물성에 미치는 영향을 조사하였다. PMMA함량에 따라 블렌드의 굴곡탄성률, 인장항복강도 및 표면광택은 증가하였으며, 파단신율 및 충격강도는 감소하였다. 카본블랙을 첨가 하였을 경우, 블렌드 물성은 전반적으로 감소하는 경향을 보였다. 아울러 사용한 ABS형태 및 카본블랙 첨가에 따른 용융거동을 조사하였다.

Two types of ABS were prepared from diffrent types of rubber, and blends of the ABS and PMMA were compounded and evaluated in terms of morphology, mechaincal and rheological properties. In addition, the effect of carbon black in the ABS/PMMA blends were studied. With increasing PMMA content, flexural modulus, tensile yield strength, and surface gloss of the blends increased, but elongation at break and Izod Impact strength decreased. With carbon black addition, mechanical properties were generally decreased. Effects of the type of ABS, and carbon black on melt properties were also studied.

[References]

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[1] "Polymer Blends," 1, D.R. Paul and S. Newman Eds., Academic Press, New York (1978)

[2] "Polymer Alloys and Blends," L.A. Utraki Eds., Hansel Publishers, New York (1990)

[3] Triacca VJ, Ziaee S, Barlow JW, Keskkulas H, Paul DR, Polymer, 32, 1401 (1991)

[4] Favis BD, Chalifoux JP, Polymer, 29, 1761 (1988)

[5] Malik TM, Carreau PJ, Chapleau N, Polym. Eng. Sci., 29, 600 (1989)

[6] Lee M, Chen S, Polym. Eng. Sci., 33, 686 (1993)

[7] Maiti SN, Saroop UK, Misra A, Polym. Eng. Sci., 32, 27 (1992)

[8] Suarez H, Barlow JW, Paul DR, J. Appl. Polym. Sci., 29, 3253 (1984)

[9] Aoki Y, Watanabe M, Polym. Eng. Sci., 32, 878 (1986)

[10] Kim Bk, Shin GS, Kim YJ, Park TS, J. Appl. Polym. Sci., 47, 1581 (1993)

[11] Kim YJ, Shin GS, Lee IT, Kim BK, J. Appl. Polym. Sci., 47, 295 (1993)

[12] Utraki LA, Dumoulin MM, Toma P, Polym. Eng. Sci., 26, 34 (1986)

[13] Utraki LA, Shi ZH, Polym. Eng. Sci., 32, 1824 (1992)

[14] Ghiam F, White JL, Polym. Eng. Sci., 31, 76 (1991)

[15] Lindt JT, Ghosh AK, Polym. Eng. Sci., 32, 1802 (1992)

[16] Manson JA, Sperling LH, "Polymer Blends and Composites," 373, Plenum Press, New York (1976)

[17] "Encyclopedia of Polymer Science and Engineering," 7, J.I, Kroschwitz, H.F. Mark, N.M. Bikales, C.G. Overberger, G. Menges Eds., Wiley Interscience, New York (1985)

[18] Nakis M, Nicolais L, J. Appl. Polym. Sci., 15, 469 (1971)

[19] Aoki Y, Macromolecules, 20, 2208 (1987)

[20] Kim H, Keskkula H, Paul DR, Polymer, 32, 1447 (1991)

[21] Bucknall CB, "Toughened Plastics," 154, Applied Science, London (1977)

[22] Meeten GH, "Optical Properties of Polymer," 327, Elsevier Applied Science, London (1986)

[23] Encyclopedia of Polymer Science and Engineering, 2, J.I, Kroschwitz, H.F. Mark, N.M. Bikales, C.G. Overberger, G. Menges Eds., Wiley Interscience, New York (1985)

[24] Gachter R, Muller H, "Plastic Additives," 648, Oxford University Press, New York (1990)

[25] White JL, "Polymer Compatibility and Incompatibility: Principles and Practices," K. Solc, ed., MMI Press, New York (1982)

[26] Suetsugu Y, White JL, J. Appl. Polym. Sci., 28, 1481 (1983)

[27] Toki S, White JL, J. Appl. Polym. Sci., 27, 3171 (1982)

[28] Chuang HK, Han CD, J. Appl. Polym. Sci., 29, 2205 (1984)

[29] Shin GS, Kim BK, J. Appl. Polym. Sci., 48, 945 (1993)

[30] Champman FM, Lee TS, Soc. Plast. Eng. J., 26, 37 (1970)