화학공학소재연구정보센터
Journal of the Korean Industrial and Engineering Chemistry, Vol.5, No.6, 981-989, December, 1994
Bentonite가 ABS 수지의 기계적 물성에 미치는 영향
Effect of Bentonite on the Mechanical Properties of ABS Resin
초록
국내에서 상당량 채취되는 자연산 bentonite(Ca계)와 이를 Na2CO3로 전환시켜 상업적으로 여러 용도에서 사용되는 Na계 bentonite를 신소재 개발을 위한 점토/유기물 복합체에 대한 고찰 측면에서 matrix 수지를 ABS로 하고 이의 충진재로의 특성을 살펴 보았다. 결과, bentonite의 함량이 증가하면 탄성율은 증가하지만 충격강도는 감소하였으며, 경도는 일정하였다. Na계 bentonite가 Ca계에 비하여 탄성율은 낮지만 충격강도에서 상대적 높은 값을 나타내었다. 저장탄성율(E')은 온도가 상승함에 따라 감소하나 tan δ는 주파수가 증가할수록 고온으로 shift되었다.
For the development of new material used bentonite in ceramic/organic material composite ABS(acrylonitrile-butadiene-styrene) material was used as a matrix polymer and a series of bentonite was blended together This bentonite, filler like talc or mica for plastic material was used since natural bentonite(Ca type) is easily obtainable in Korea, Na-bentonite changed from natural bentonite by Na2CO3 based on the specified compositions changes in the static and dynamic mechanical properties. It was discovered that the increased content of natural and Na- bentonite results in higher modulus with reduced impact strength. And Rockwell hardness was constant And Na- bentonite filled polymer showed improvement in impact strength and lower in modulus as the natural bentonite filled polymer. The storage modulus(E') of Na- bentonite filled ABS resin was higher than that of Ca- bentonite filled ABS resin, while higher temperature, storage modulus(E') decreased. At higher frequency, tan δ peak was shifted at high temperature.
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