운모상에 인산아연이 도포된 방청안료의 제조 및 성능평가

이유진; 박성수; 홍성수; 이승호; 김대성; 이근대; Yu Jin Lee; Seong Soo Park; Seong Soo Hong; Seung Ho Lee; Dae Sung Kim; Gun Dae Lee

Clean Technology, Vol.19, No.3, 257-263, September, 2013

DOI10.7464/ksct.2013.19.3.257 Export Citation

운모상에 인산아연이 도포된 방청안료의 제조 및 성능평가

Preparation and Performance Evaluation of Zinc Phosphate-Coated Mica Anticorrrosive Pigment

이유진, 박성수 , 홍성수 , 이승호 ¹, 김대성¹, 이근대 ^†

부경대학교 공업화학과, 화학공학과, 608-739 부산광역시 남구 용당동 산 100
¹한국세라믹기술원 에코복합소재센터, 153-801 서울특별시 금천구 가산동 233-5

Yu Jin Lee, Seong Soo Park , Seong Soo Hong , Seung Ho Lee¹, Dae Sung Kim¹, and Gun Dae Lee^†

Department of Industrial Chemistry, Department of Chemical Engineering, Pukyong National University, San 100, Yongdang-dong, Nam-gu, Busan 608-739, Korea
¹Eco Composite Materials Center, Korea Institute of Ceramic Engineering & Technology, 233-5 Gasan-dong, Guemcheon-gu, Seoul 153-801, Korea

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초록

인산아연이 도포된 운모 안료(ZP/mica)를 인산, 질산아연 그리고 운모를 출발물질로 하여 제조한 후, 방청안료로 사용하였다. 주사전자현미경 및 X-선 회절분석기 등을 이용하여 제조된 안료의 형상과 결정구조를 관찰하였다. 제조된 안료와 에폭시수지를 배합하여 도막을 형성시킨 다음 전기화학적 임피던스법을 이용하여 안료의 방청성을 평가하였다. 70 ℃에서 합성된 ZP/mica 안료의 방청성이 20 ℃에서 제조된 안료보다는 우수하다는 것을 알 수 있었다. 70 ℃에서 합성된 ZP/mica 안료표면에는 Zn3(PO4)2ㆍ2H2O 이외에도 ZnO가 동시에 생성되어 있음을 볼 수 있었다. 합성된 ZP/mica 안료의 우수한 방청성은 운모표면의 아연화합물에 의한 전기화학적 방청기구와 판상구조의 운모에 의한 장벽 방청기구의 상승작용에 기인한 것으로 생각된다.

The zinc phosphate-coated mica (ZP/mica) pigments were prepared using phosphoric acid, zinc nitrate and mica as starting materials, and used as anticorrosive pigments. The scanning electron microscopy (SEM) and x-ray diffraction (XRD) techniques were used to observe the morphology and crystal structure of prepared pigments. The prepared pigments were incorporated into an epoxy binder to prepare coating and the corrosion inhibition performance of the pigments was evaluated using electrochemical impedance spectroscopy (EIS). It was found that the anticorrosive performance of the ZP/mica pigment prepared at 70 ℃was the better than that prepared at 20 ℃. The formation of ZnO, in addition to Zn3(PO4)2ㆍH2O, was observed on ZP/mica pigment prepared at 70 ℃. The excellent anticorrosive performance of ZP/mica pigment could be ascribed to the synergistic effect with electrochemical anticorrosive mechanism from zinc compounds on mica and barrier anticorrosive mechanism from lamellar mica.

Keywords:Zinc phosphate;Mica;Anticorrosive pigment;Electrochemical mechanism;Barrier mechanism

[References]

Lima-Netoa P, Araujob AP, Araujob WS, Correiaa AN, Prog. Org. Coat., 62, 344 (2008)
Zubielewicz M, Gnot W, Prog. Org. Coat., 49, 358 (2004)
Kalendova A, Kalenda P, Vesely D, Prog. Org. Coat., 57, 1 (2006)
Naderi R, Attar MM, Electrochim. Acta, 53(18), 5692 (2008)
Beiro M, Collazo A, Izquierdo M, Novoa XR, Perez C, Prog. Org. Coat., 46, 97 (2003)
Austin MJ, “Inorganic Anticorrosive Pigments,” in Koleske JV (Ed.), The Gardner Sward Handbook: Paint and Coating Testing Manual, vol. 17, 14th ed., ASTM Manual, MNL, 238 (1995)
Hare CH, Kurnas JS, J. Coat. Technol., 72, 21 (2000)
Mahdavian M, Attar MM, Electrochim. Acta, 50(24), 4645 (2005)
Deya MC, Blustein G, Romagnoli R, del Amo B, Surf. Coat. Technol., 150, 133 (2002)
Singh L, Kaur N, Singh M, Indian J. Pure Appl. Phys., 50, 14 (2012)
Pawlig O, Trettin R, Mater. Res. Bull., 34(12-13), 1959 (1999)
Stoch A, Paluszkiewicz C, Dlugon E, J. Mol. Structure., 511, 295 (1999)
Fedrizzi L, Tomasi A, Pedrotti S, Bonora PL, Balboni P, J. Mater. Sci., 24, 3928 (1989)
Liu Z, Li J, Ya J, Xin Y, Jin Z, Mater. Lett., 62, 1190 (2008)
Prasad V, Shaikh AJ, Kathe AA, Bisoyi DK, Verma AK, Vigneshwaran N, J.Mater. Process. Technol., 210, 1962 (2010)
Park JH, Lee GD, Nishikata A, Tsuru T, Corros. Sci., 44, 1087 (2002)
Xu A, Zhang F, Luo B, Jin F, Zhang T, Int. J. Electrochem. Sci., 8, 773 (2013)
Choi H, Kim KY, Park JM, Prog. Org. Coat., 76, 1316 (2013)
Keresse P, Szadkowski V, Odenthal RH, Influence of Pigmetns on The Effectiveness of Anticorrosive Primes, in Leidheiser H.(Ed.), Corrosion control by organic coatings, NACE, Houston, 197 (1981)
Jagtap RN, Patil PP, Hassan SZ, Prog.Org. Coat., 63, 389 (2008)
Shi X, Nguyen TA, Suo Z, Liu Y, Avci R, Surf. Coat. Technol., 204, 237 (2009)

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[2] Zubielewicz M, Gnot W, Prog. Org. Coat., 49, 358 (2004)

[3] Kalendova A, Kalenda P, Vesely D, Prog. Org. Coat., 57, 1 (2006)

[4] Naderi R, Attar MM, Electrochim. Acta, 53(18), 5692 (2008)

[5] Beiro M, Collazo A, Izquierdo M, Novoa XR, Perez C, Prog. Org. Coat., 46, 97 (2003)

[6] Austin MJ, “Inorganic Anticorrosive Pigments,” in Koleske JV (Ed.), The Gardner Sward Handbook: Paint and Coating Testing Manual, vol. 17, 14th ed., ASTM Manual, MNL, 238 (1995)

[7] Hare CH, Kurnas JS, J. Coat. Technol., 72, 21 (2000)

[8] Mahdavian M, Attar MM, Electrochim. Acta, 50(24), 4645 (2005)

[9] Deya MC, Blustein G, Romagnoli R, del Amo B, Surf. Coat. Technol., 150, 133 (2002)

[10] Singh L, Kaur N, Singh M, Indian J. Pure Appl. Phys., 50, 14 (2012)

[11] Pawlig O, Trettin R, Mater. Res. Bull., 34(12-13), 1959 (1999)

[12] Stoch A, Paluszkiewicz C, Dlugon E, J. Mol. Structure., 511, 295 (1999)

[13] Fedrizzi L, Tomasi A, Pedrotti S, Bonora PL, Balboni P, J. Mater. Sci., 24, 3928 (1989)

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