화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.19, No.6, 1858-1868, November, 2013
Effect of calcination and reaction conditions on the catalytic performance of Co-Ni/Al2O3 catalyst for CO hydrogenation
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The Co-Ni/Al2O3 catalysts prepared using impregnation procedure, were used for the Fischer-Tropsch synthesis. The effect of calcination conditions of the catalyst as well as reactor situation was studied. It was found that the catalyst calcined at 550 ℃ for 6 h in air atmosphere has shown the best catalytic performance for CO hydrogenation. The best operational conditions were obtained as following: T = 350 ℃, P = 1 atm and H2/CO = 2/1.
  1. Ding M, Yang Y, Xu J, Tao ZC, Wang HL, Wang H, Xiang HW, Li YW, Appl. Catal. A: Gen., 345(2), 176 (2008)
  2. Schulz H, Applied Catalysis A: General., 1186, 3 (1999)
  3. Wang C, Xu L, Wang Q, Journal of Natural Gas Chemistry., 12, 10 (2003)
  4. Li XH, Luo MF, Asami K, Catal. Today, 89(4), 439 (2004)
  5. Duvenhage DJ, Coville NJ, Appl. Catal. A: Gen., 233(1-2), 63 (2002)
  6. Jothimurugesan K, Gangwal SK, Industrial and Engineering Chemistry Research., 37 (1181)
  7. Cooper M, Frost J, Applied Catalysis A: General., 57, L5 (1990)
  8. Stoop F, Wiele KV, Applied Catalysis A: General., 23, 35 (1986)
  9. Arakawa H, Kiyozumi Y, Chemistry Letters., 176, 1341 (1986)
  10. Mirzaei AA, Galavy M, Beigbabaei A, Eslamimanesh V, Journal of the Iranian Chemical Society., 4, 347 (2007)
  11. Dimitrova PG, Mehandjiev DR, Journal of Catalysis., 4, 356 (1994)
  12. Lapszewicz JA, Loeh HJ, Chipperfield JR, Journal of the Chemical Society:Chemical Communications., 11, 913 (1993)
  13. Spadaro L, Arena F, Granados ML, Ojeda M, Fierro JLG, Frusteri F, J. Catal., 234(2), 451 (2005)
  14. Bessell B, Applied Catalysis A: General., 96, 253 (1993)
  15. Mirzaei AA, Galavy M, Eslamimanesh V, Australian Journal of Chemistry., 61, 144 (2008)
  16. Yang Y, Xiang HW, Xu YY, Bai L, Li YW, Appl. Catal. A: Gen., 266(2), 181 (2004)
  17. Arsalanfar M, Mirzaei AA, Bozorgzadeh HR, Journal of Natural Gas Science and Engineering., 6, 1 (2012)
  18. Arsalanfar M, Mirzaei AA, Bozorgzadeh HR, Atashi H, Shahriari S, Pourdolat A, Natural Gas Science and Engineering., 9, 119 (2012)
  19. Beigbabaei A, Mirzaei AA, Galavy M, Youssefi A, Open Catalysis Journal., 3, 71 (2010)
  20. Mirzaei AA, Babaei AB, Galavy M, Youssefi A, Fuel Process. Technol., 91(3), 335 (2010)
  21. Tian L, Huo CF, Cao DB, Yang Y, Xu J, Wu BS, Xiang HW, Xu YY, Li YW, Journal of Molecular Structure: THEOCHEM., 941, 30 (2010)
  22. Barrault J, Forquy C, Perrichon V, Applied Catalysis A: General., 5, 119 (1983)
  23. Liu Y, Teng BT, Guo XH, Li Y, Chang J, Tian L, Hao X, Wang Y, Xiang HW, Xu YY, Li YW, J. Mol. Catal. A-Chem., 272(1-2), 182 (2007)
  24. Gribval-Constant A, Khodakov AY, Bechara R, Zholobenko VL, Studies in Surface Science and Catalysis., 144, 609 (2002)