Physical-chemical property and activity evaluation of LaB0.5Co0.5O3 (B = Cr, Mn, Cu) and LaMnxCo1-xO3 (x = 0.1, 0.25, 0.5) nano perovskites in VOC combustion

Seyed Ali Hosseini; Dariush Salari; Aligholi Niaei; Samira Arefi Oskoui

Journal of Industrial and Engineering Chemistry, Vol.19, No.6, 1903-1909, November, 2013

DOI10.1016/j.jiec.2013.02.034 Export Citation

Physical-chemical property and activity evaluation of LaB0.5Co0.5O3 (B = Cr, Mn, Cu) and LaMnxCo1-xO3 (x = 0.1, 0.25, 0.5) nano perovskites in VOC combustion

Seyed Ali Hosseini^{1, 2}, Dariush Salari², Aligholi Niaei^{2, †}, and Samira Arefi Oskoui²

¹Department of Chemistry, Faculty of Science, University of Urmia, Orumiyeh, Iran
²Department of Applied Chemistry and Chemical Engineering, Faculty of Chemistry, University of Tabriz, 5166616471 Tabriz, Iran

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The correlation between physical-chemical properties and activities of LaB0.5Co0.5O3 (B = Cr, Mn, Cu) nano perovskites was studied in combustion of toluene. LaMn0.5Co0.5O3 showed the highest activity among LaB0.5Co0.5O3 catalysts and further optimization study was focused on LaMnxCo1-xO3 (x = 0.1, 0.25, 0.5). The activity and reducibility of catalysts improved due to partial substitution of Co3+ by B cation. No direct relationship was between surface area and catalyst activity. T50% of 2-propanol over LaMn0.25Co0.75O3, LaMn0.5Co0.5O3, LaMn0.1Co0.9O3 and LaCoO3 was 168, 200, 220 and 229 ℃, respectively. LaMn0.25Co0.75O3 was the optimum catalyst and showed robust stability in combustion of toluene and 2-propanol.

Keywords:LaB0.5Co0.5O3 perovskite;Sol-gel auto combustion;Nano mixed oxides;Volatile organic compounds;TPR

[References]

Izadkhah B, Nabavi SR, Niaei A, Salari D, Mahmuodi Badiki T, C¸aylak N, Journal of Industrial and Engineering Chemistry., 18 (2012)
Kim J, Park J, Kim HS, Yoo YJ, Journal of Industrial and Engineering Chemistry., 18 (2012)
Merino N, Barbero BP, Grange P, Cadu´ s LE, Journal of Catalysis., 231 (2005)
Garten RL, Dalla Betta RA, Schlatter JC, in: Ertl G, Knozinger H, Wertkamp J (Eds.), Handbook of Heterogeneous Catalysis, vol. 4, VHC, Weinheim, Germany (1998)
Tejuca LG, Fierro JLG (Eds.), Properties and Applications of Perovskite-type Oxides, Dekker, New York (1993)
Alifanti M, Florea M, Somacescu S, Parvulescu VI, Applied Catalysis B., 60 (2005)
Zhang HM, Shimizu Y, Teraoka Y, Miura N, Yamazoe N, Journal of Catalysis., 121 (1990)
Ferri D, Forni L, Applied Catalysis B., 16 (1998)
Gallagher P, Johnson D, Vogel E, Journal of the American Ceramic Society., 60 (1997)
Levasseur B, Kaliaguine S, Applied Catalysis B., 88 (2009)
Abdolrahmani M, Parvari M, Habibpoor M, Chinese Journal of Catalysis., 31 (2010)
Hosseini SA, Sadeghi MT, Alemi A, Niaei A, Salari D, Ahmadi L, Chinese Journal of Catalysis., 34 (2010)
Bosomoiu M, Bozga G, Berger D, Matei C, Applied Catalysis B., 84 (2008)
Nitadori T, Ichiki T, Misono M, Bulletin of the Chemical Society of Japan., 61 (1988)
Seyfia B, Baghalhaa M, Kazemian H, Chemical Engineering Journal., 148 (2009)
Centi G, Lanzafame P, Perathoner S, Catalysis Today., 99 (2005)
Hosseini SA, Salari D, Niaei A, Deganello F, Pantaleo G, Hojati P, Journal of Environmental Science and Health. Part A, Toxic/Hazardous Substances and Environmental Engineering., 46 (2011)
Deganello F, Marcı` G, Deganello G, Journal of the European Ceramic Society., 29 (2009)
A´ lvarez-Galva´ n MC, de la Pen.a O‘Shea VA, Arzamendi G, Pawelec B, Gandı´a LM, Fierro JLG, Applied Catalysis B., 92 (2009)
Liang JJ, Weng HS, Journal of Chemical Reviews., 101 (2001)
Kojima I, Adachi H, Yasumori I, Surface Science., 130 (1983)
Tanaka H, Misono M, Current Opinion in Solid State and Materials Science Journal., 5 (2001)
Pecchi G, Reyes P, Zamora R, Cadu´ s L, Fierro J, Journal of Solid State Chemistry., 181 (2008)
Pena M, Fierro JL, Journal of Chemical Reviews., 101 (2001)
Abadian L, Malekzadeh A, Khodadadi AA, Mortazavi Y, Applied Surface Science., 243 (2005)
Fierro JLG, Tascon J, Tejuca L, Journal of Catalysis., 89 (1984)
Ifrah S, Kaddouri A, Gellin P, Bergeret G, Catalysis Communications., 8 (2007)
Huang L, Bassir M, Kaliaguine S, Applied Surface Science., 243 (2005)
Huang H, Liu Y, Tang W, Chen Y, Catalysis Communications., 9 (2008)

[Referenced By]

[1] Izadkhah B, Nabavi SR, Niaei A, Salari D, Mahmuodi Badiki T, C¸aylak N, Journal of Industrial and Engineering Chemistry., 18 (2012)

[2] Kim J, Park J, Kim HS, Yoo YJ, Journal of Industrial and Engineering Chemistry., 18 (2012)

[3] Merino N, Barbero BP, Grange P, Cadu´ s LE, Journal of Catalysis., 231 (2005)

[4] Garten RL, Dalla Betta RA, Schlatter JC, in: Ertl G, Knozinger H, Wertkamp J (Eds.), Handbook of Heterogeneous Catalysis, vol. 4, VHC, Weinheim, Germany (1998)

[5] Tejuca LG, Fierro JLG (Eds.), Properties and Applications of Perovskite-type Oxides, Dekker, New York (1993)

[6] Alifanti M, Florea M, Somacescu S, Parvulescu VI, Applied Catalysis B., 60 (2005)

[7] Zhang HM, Shimizu Y, Teraoka Y, Miura N, Yamazoe N, Journal of Catalysis., 121 (1990)

[8] Ferri D, Forni L, Applied Catalysis B., 16 (1998)

[9] Gallagher P, Johnson D, Vogel E, Journal of the American Ceramic Society., 60 (1997)

[10] Levasseur B, Kaliaguine S, Applied Catalysis B., 88 (2009)

[11] Abdolrahmani M, Parvari M, Habibpoor M, Chinese Journal of Catalysis., 31 (2010)

[12] Hosseini SA, Sadeghi MT, Alemi A, Niaei A, Salari D, Ahmadi L, Chinese Journal of Catalysis., 34 (2010)

[13] Bosomoiu M, Bozga G, Berger D, Matei C, Applied Catalysis B., 84 (2008)

[14] Nitadori T, Ichiki T, Misono M, Bulletin of the Chemical Society of Japan., 61 (1988)

[15] Seyfia B, Baghalhaa M, Kazemian H, Chemical Engineering Journal., 148 (2009)

[16] Centi G, Lanzafame P, Perathoner S, Catalysis Today., 99 (2005)

[17] Hosseini SA, Salari D, Niaei A, Deganello F, Pantaleo G, Hojati P, Journal of Environmental Science and Health. Part A, Toxic/Hazardous Substances and Environmental Engineering., 46 (2011)

[18] Deganello F, Marcı` G, Deganello G, Journal of the European Ceramic Society., 29 (2009)

[19] A´ lvarez-Galva´ n MC, de la Pen.a O‘Shea VA, Arzamendi G, Pawelec B, Gandı´a LM, Fierro JLG, Applied Catalysis B., 92 (2009)

[20] Liang JJ, Weng HS, Journal of Chemical Reviews., 101 (2001)

[21] Kojima I, Adachi H, Yasumori I, Surface Science., 130 (1983)

[22] Tanaka H, Misono M, Current Opinion in Solid State and Materials Science Journal., 5 (2001)

[23] Pecchi G, Reyes P, Zamora R, Cadu´ s L, Fierro J, Journal of Solid State Chemistry., 181 (2008)

[24] Pena M, Fierro JL, Journal of Chemical Reviews., 101 (2001)

[25] Abadian L, Malekzadeh A, Khodadadi AA, Mortazavi Y, Applied Surface Science., 243 (2005)

[26] Fierro JLG, Tascon J, Tejuca L, Journal of Catalysis., 89 (1984)

[27] Ifrah S, Kaddouri A, Gellin P, Bergeret G, Catalysis Communications., 8 (2007)

[28] Huang L, Bassir M, Kaliaguine S, Applied Surface Science., 243 (2005)

[29] Huang H, Liu Y, Tang W, Chen Y, Catalysis Communications., 9 (2008)