화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.19, No.6, 1981-1989, November, 2013
DOI10.1016/j.jiec.2013.03.007  Export Citation
Comparison of RSM and ANN for the investigation of linear alkylbenzene synthesis over H14[NaP5W30O110]/SiO2 catalyst
A. Hafizi, A. Ahmadpour1, †, M. Koolivand-Salooki2, M.M. Heravi3, and F.F. Bamoharram4
  • Department of Chemical Engineering, School of Chemical and Petroleum Engineering, Shiraz University, Shiraz 71345, Iran
  • 1Department of Chemical Engineering, Faculty of Engineering, Ferdowsi University of Mashhad, Mashhad, Iran
  • 2Petroleum Department, National Iranian South Oil Field Company, Ahwaz, Iran
  • 3Department of Chemistry, School of Science, Alzahra University, Tehran, Iran
  • 4Department of Chemistry, Mashhad Branch-Islamic Azad University, Mashhad, Iran
E-mail:
Design of experiments (DOE) and artificial neural networks (ANNs) were successfully applied for studying the operating parameters of benzene alkylation with 1-decene over H14[NaP5W30O110]/SiO2 catalyst. In this reaction catalyst loading, catalyst weight percent and benzene to 1-decene molar ratio (Bz/C10) were chosen as independent variables in experimental design. Prediction of 1-decene conversion and 2-phenyldecane selectivity was performed applying response surface method (RSM) and ANN models. Final selected multi-layer (3-6-2-2) ANN model resulted a coefficient of determination (R2) of 0.95 for 1-decene conversion and 0.99 for 2-phenyldecane selectivity, while the R2 of RSM was 0.93 and 0.92 for these two parameters.
Keywords:Linear alkylbenzene;RSM;ANN;Preyssler heteropoly acid;Silica-supported catalyst
  1. Kocal JA, Vora BV, Imai T, Appl. Catal. A: Gen., 221(1-2), 295 (2001)
  2. Cao Y, Kessas R, Naccache C, Ben Taarit Y, Appl. Catal. A: Gen., 184(2), 231 (1999)
  3. Hernandez-Cortez JG, Martinez L, Soto L, Lopez A, Navarrete J, Manriquez M, Lara VH, Lopez-Salinas E, Catal. Today, 150(3-4), 346 (2010)
  4. Guerra SR, Merat LMOC, San Gil RAS, Dieguez LC, Catalysis Today., 133-135, 223 (2008)
  5. Cai X, Cui S, Qu L, Yuan D, Lu B, Cai Q, Catalysis Communications., 9, 1173 (2008)
  6. Tian Z, Qin Z, Dong M, Wang G, Wang J, Catalysis Communications., 6, 385 (2005)
  7. Benlounes O, Cheknoun S, Mansouri S, Rabia C, Hocine S, Journal of the Taiwan Institute of Chemical Engineers., 42, 132 (2011)
  8. Heravi MM, Bamoharram FF, Rajabzadeh G, Seifi N, Khatami M, J. Mol. Catal. A-Chem., 259(1-2), 213 (2006)
  9. Bhatt N, Patel A, Journal of the Taiwan Institute of Chemical Engineers., 42, 356 (2011)
  10. Devassy BM, Lefebvre F, Bohringer W, Fletcher J, Halligudi SB, J. Mol. Catal. A-Chem., 236(1-2), 162 (2005)
  11. Bamoharram FF, Heravi MM, Roshani M, Jahangir M, Gharib A, Journal of Molecular Catalysis A: Chemical., 271, 271 (2007)
  12. Bamoharram FF, Heravi MM, Roshani M, Abrishami F, J. Mol. Catal. A-Chem., 267(1-2), 241 (2007)
  13. Bhorodwaj SK, Dutta DK, Appl. Catal. A: Gen., 378(2), 221 (2010)
  14. Alhanash A, Kozhevnikova EF, Kozhevnikov IV, Appl. Catal. A: Gen., 378(1), 11 (2010)
  15. Zhang Z, Peng J, Qu W, Zhang L, Zhang Z, Li W, Wan R, Journal of the Taiwan Institute of Chemical Engineers., 40, 541 (2009)
  16. Zabeti M, Daud WMAW, Aroua MK, Appl. Catal. A: Gen., 366(1), 154 (2009)
  17. Gunay ME, Yildirim R, Appl. Catal. A: Gen., 377(1-2), 174 (2010)
  18. Corma A, Serra JM, Serna P, Valero S, Argente E, Botti V, J. Catal., 229(2), 513 (2005)
  19. Holena M, Baerns M, Catal. Today, 81(3), 485 (2003)
  20. Alamolhoda S, Kazemeini M, Zaherian A, Zakerinasab MR, J. Ind. Eng. Chem., 18(6), 2059 (2012)
  21. Guaracho VV, Kaminari NMS, Ponte MJJS, Ponte HA, J. Hazard. Mater., 172(2-3), 1087 (2009)
  22. Tiwari BK, Muthukumarappan K, Donnell CPO, Cullen PJ, Journal of Food Engineering., 88, 553 (2008)
  23. Gholami RM, Mousavi SM, Borghei SM, J. Ind. Eng. Chem., 18(1), 218 (2012)
  24. Khayet M, Abu Seman MN, Hilal N, J. Membr. Sci., 349(1-2), 113 (2010)
  25. Bollas GM, Papadokonstadakis S, Michalopoulos J, Arampatzis G, Lappas AA, Vasalos IA, Lygeros A, Chem. Eng. Process., 42(8-9), 697 (2003)
  26. Callan R, The Essence of Neural Networks, Prentice Hall, Hertfordshire (1999)
  27. Wang X, Luo R, Shao H, Designing a soft sensor for a distillation column with the fuzzy distributed radial basis function neural network, 1714 (1996)
  28. Bera AK, Ghosh A, Ghosh A, Geotextiles and Geomembranes., 23, 261 (2005)
  29. Alizadeh MH, Razavi H, Bamoharram FF, Hassanzadeh MK, Khoshnavazi R, Mohammadi Zonoz F, Kinetics and Catalysis., 44, 524 (2003)
  30. Hafizi A, Ahmadpour A, Heravi MM, Bamoharram FF, Khosroshahi M, Chinese Journal of Catalysis., 33, 494 (2012)
  31. Tan IAW, Ahmad AL, Hameed BH, Chem. Eng. J., 137(3), 462 (2008)
  32. Campolongo F, Braddock R, Reliability Engineering & System Safety., 64, 1 (1999)