Thermodynamic analysis of steam and aqueous reforming of hydroxylated C6 aliphatic compounds

Jin-Woo Jun; Young-Woong Suh; Dong Jin Suh; Yong-Kul Lee

Journal of Industrial and Engineering Chemistry, Vol.19, No.6, 2072-2078, November, 2013

DOI10.1016/j.jiec.2013.03.020 Export Citation

Thermodynamic analysis of steam and aqueous reforming of hydroxylated C6 aliphatic compounds

Jin-Woo Jun^{1, 2}, Young-Woong Suh³, Dong Jin Suh², and Yong-Kul Lee^{1, †}

¹Laboratory of Advanced Catalysis for Energy and Environment, Department of Chemical Engineering, Dankook University, 126 Jukjeondong, Yongin 448-701, Republic of Korea
²Clean Energy Center, Korea Institute of Science and Technology, Seoul 136-791, Republic of Korea
³Department of Chemical Engineering, Hanyang University, Seoul 133-791, Republic of Korea

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Six-carbon containing model compounds of 1-hexanol, 1,6-hexanediol and sorbitol for the reforming were employed to study the effect of hydroxyl functional group on the thermodynamic equilibrium product distribution in a wide range of conditions of temperature (300-1300 K), pressure (1-150 atm) and feed composition (H2O/carbon = 0.5.30). The increase of hydroxyl group in reactants gave rise to the increase of carbon dioxide with loss of methane in the product in the following order: sorbitol > 1,6-hexanediol > 1-hexanol, while the formation of hydrogen and carbon monoxide was mostly governed by the feed composition (H2O/carbon) and pressure rather than the number of hydroxyl group in reactants.

Keywords:Thermodynamic analysis;1-Hexanol;1,6-Hexanediol;Sorbitol;Reforming

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