Removal of 4-nitro-phenol from wastewater using synthetic zeolite and kaolin clay

Nada Sadoon Ahmedzeki; Haider Abdulkarem Rashid; Asir Abduljabbar Alnaama; Maha Hadi Alhasani; Zainab Abdulhussain

Korean Journal of Chemical Engineering, Vol.30, No.12, 2213-2218, December, 2013

DOI10.1007/s11814-013-0165-x Export Citation

Removal of 4-nitro-phenol from wastewater using synthetic zeolite and kaolin clay

Nada Sadoon Ahmedzeki^†, Haider Abdulkarem Rashid, Asir Abduljabbar Alnaama, Maha Hadi Alhasani, and Zainab Abdulhussain

Chemical Engineering Department, College of Engineering, University of Baghdad, Iraq

E-mail:

Adsorption techniques are widely used to remove certain classes of pollutants from wastewater. Phenolic compounds represent one of the problematic groups. Na-Y zeolite has been synthesized from locally available Iraqi kaolin clay. Characterization of the prepared zeolite was made by XRD and surface area measurement using N2 adsorption. Both synthetic Na-Y zeolite and kaolin clay have been tested for adsorption of 4-Nitro-phenol in batch mode experiments. Maximum removal efficiencies of 90% and 80% were obtained using the prepared zeolite and kaolin clay, respectively. Kinetics and equilibrium adsorption isotherms were investigated. Investigations showed that both Langmuir and Freundlich isotherms fit the experimental data quite well. On the other hand, the adsorption of phenol was found to obey first-order kinetics.

Keywords:Pollutants;Phenolic Compounds;Adsorption;Zeolite Na-Y

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[Referenced By]

[1] Ahmaruzzaman Md, J. Adv. Col. Inter. Sci., 14348-67 (2008)

[2] Gupta VK, Ali I, Int. J. Environ. Pollut., 38, 4012 (2006)

[3] Htay MM, Oo MM, World Academy of Science, Engineering and Technology., 48 (2008)

[4] Ghobarkar H, Schaf O, Guth U, Prog. Solid State Chem., 27, 29 (1999)

[5] Sircar Sh. Myers A, Handbook of zeolite science and technology, Chapter 22, Marcel Dekker, Inc. (2003)

[6] Breck DW, Zeolites molecular sieves structure chemistry and use, Wiley, New York (1984)

[7] D´yaz E, Ord´o.nez S, Veg A, Coca J, J. Chromatography., A1049, 139 (2004)

[8] Kozhevnikov SA, Motovilova NN, Sibarov DA, Vinogradov MW, J. Appl. Chem., USSR (engl. Transl.); 58: 1412 (Cited in Ahmaruzzaman 2008, Ref #39). (1985)

[9] Su F, Lu L, Tee Meng H, Zhao XS, Carbon., 43, 1156 (2005)

[10] Sherman JD, National Academy of Science (Colloquium Paper)., 96, 3471 (1999)

[11] Chen NY, Garwood WE, Dwyer FG, Shape selective catalyst in industrial applications, Dekker, New York, 1 (1989)

[12] Zielke RC, Pinnavaia TJ, Clays and Clay Minerals., 36(5), 403 (1988)

[13] Ma M, Cui L, Dong Y, Wang T, Da C, Hirasaki GJ, Biswal SL, J. Colloid Interface Sci., http://dx.doi.org/10.1016/j.jcis.2013.07.006 (2013)

[14] Schofield RK, J. Soil Sci., 1(1), 1 (1950)

[15] Bolland MDA, Posner AM, Quirk JP, Clays Clay Miner., 28, 412 (1980)

[16] An JH, Dultz S, Appl. Clay Sci., 36(4), 256 (2007)

[17] Shichi T, Takagi K, J. Photochem Photobiol C Photochem Rev., 1 (2000)

[18] Ralph EG, Clay Mineralogy, 2nd Ed. Int. Series in the Earth and Planetary Sciences (1968)

[19] Haden WL, Metuchen Dzierzanowski FJ, Methods for making synthetic zeolitic material, US Patent, 2,992,068 (1961)

[20] Mbadcam JK, Anagho SG, Nsami N, Kammegne AM, J.Environ. Chem. Ecotoxicol., 3(11), 290 (2011)

[21] Lucas S, Cocero MJ, Zetzl C, Brunner G, Fluid Phase Equilib., 219(2), 171 (2004)

[22] Weber J, Walter Jr., Physicochemical Processes Water Quality Control Ed., Wiley (1972)

[23] Tan IAW, Ahmad AL, Hameed BH, Desalination, 225(1-3), 13 (2008)

[24] Kareem Kh. Ez., Fluid catalytic cracking of petroleum fraction (vacuum gas oil) to produce gasoline, PhD. Thesis University of Baghdad (2010)

[25] Haden WL, Metuchen J, Dzierzanowski FJ, Somerset NJ, Method For Making a Faujasite-Type Crystalline Zeolite, US Patent,3,338,672 (1967)

[26] Treacy MMJ, Higgins JB, Collection of simulated XRD powder patterns for zeolites, Published on behalf of the Structure Commission of the International Zeolite Association, Fourth Revised Edition, ELSEVIER (2001)

[27] Christidis GE, Papantoni H, The Open Mineralogy Journal, 2, 1-5 1,1874-4567/08. Bentham Science Publishers Ltd. (2008)

[28] Jeppu JP, Clement TP, J. Contaminant Hydrol., 129, 46 (2012)

[29] Potgieter JH, Bada SO, Potgieter-Vermaak SS, Water SA., 35(1) (2009)

[30] Wu J, Yu HQ, J. Hazard. Mater. B., 498-508, 137 (2006)

[31] Batabyal D, Sahu A, Chaudhuri SK, Sep. Technol., 5(4), 179 (1995)