Flexible clay hybrid films with various poly(vinyl alcohol) contents: Thermal properties, morphology, optical transparency, and gas permeability

Jieun Shin; Jeong-Cheol Kim; Jin-Hae Chang

Macromolecular Research, Vol.21, No.12, 1349-1354, December, 2013

DOI10.1007/s13233-013-1182-7 Export Citation

Flexible clay hybrid films with various poly(vinyl alcohol) contents: Thermal properties, morphology, optical transparency, and gas permeability

Jieun Shin, Jeong-Cheol Kim¹, and Jin-Hae Chang^{2, †}

Center for Scientific Instruments, Kumoh National Institute of Technology, Gyeongbuk, 730-701, Korea
¹Energy and Applied Optics Team, Korea Institute of Industrial Technology, Gwangju, 500-480, Korea
²School of Energy and Integrated Materials Engineering, Kumoh National Institute of Technology, Gyeongbuk, 730-701, Korea

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Clay hybrid films were obtained by the solution blending of saponite (SPT) with various amounts of poly(vinyl alcohol) (PVA). Variations in the thermal properties, morphology, optical transparency, and gas permeability of the clay hybrid films with PVA content in the range 0?10 wt% were examined. With increasing PVA content, the thermal transition temperatures of the hybrids decreased. However, the values of the coefficient of thermal expansion (CTE) increased gradually. The values of the yellow index (YI) and oxygen transmission rate (O2TR) of the clay hybrid films remained constant regardless of their PVA content.

Keywords:saponite;poly(vinyl alcohol) (PVA);hybrid;flexible film

[References]

Ratna D, Divekar S, Samui AB, Chakraborty BC, Banthia AK, Polymer, 47(11), 4068 (2006)
Kawasaki K, Ebina T, Mizukami F, Tsuda H, Motegi K, Appl. Clay Sci., 48, 111 (2010)
Manias E, Touny A, Wu L, Strawhecker K, Lu B, Chung TC, Chem. Mater., 13, 3516 (2001)
Cendoya I, Lopez D, Alegria A, Mijangos C, J. Polym. Sci. B: Polym. Phys., 39(17), 1968 (2001)
Legaly G, Smectitic Clays as Ionic Macromolecules, Elsevier, London, 1986, p 77.
Suzuki F, Nakane K, Piao JS, J. Mater. Sci., 31(5), 1335 (1996)
Chang JH, Jang TG, Ihn KJ, Lee WK, Sur GS, J. Appl. Polym. Sci., 90(12), 3208 (2003)
Gilman JW, Appl. Clay Sci., 15, 31 (1999)
Kojima Y, Usuki A, Kawasumi M, Okada A, J. Mater. Res., 8, 1185 (1993)
LeBaron PC, Wang Z, Thomas JP, Appl. Clay Sci., 15, 11 (1999)
Yano K, Usuki A, Karauchi T, Kamigaito O, J. Polym. Sci. A: Polym. Chem., 31, 2493 (1993)
Messersmith PB, Giannelis EP, Chem. Mater., 5, 1064 (1993)
Strawhecker KE, Manias E, Chem. Mater., 12, 2943 (2000)
Jeon HJ, Youk JH, Yu WR, Macromol. Res., 18(5), 458 (2010)
Nakane K, Yamashita T, Iwakura K, Suzuki F, J. Appl. Polym. Sci., 74(1), 133 (1999)
Chuang WY, Young TH, Chiu WY, Lin CY, Polymer, 41(15), 5633 (2000)
Huang S, Yang Z, Zhu H, Ren L, Tjiu WW, Liu T, Macromol. Res., 20(6), 568 (2012)
Kokabi M, Sirousazar M, Hassan ZM, Eur. Polym. J., 43, 773 (2007)
Zhen W, Lu C, Li C, Liang M, Appl. Clay Sci., 57, 64 (2012)
Huang HD, Ren PG, Chen J, Zhang WQ, Ji X, Li ZM, J. Membr. Sci., 409-410, 156 (2012)
Xu Y, Hong W, Bai H, Li C, Shi G, Carbon, 47, 3538 (2009)
Gilman JW, Jackson CL, Morgan AB, Harris R, Chem. Mater., 12, 1866 (2000)
Ebina T, Mizukami F, Adv. Mater., 19(18), 2450 (2007)
Nam HJ, Ishii R, Ebina T, Mizukami F, Mater. Lett., 63, 54 (2009)
Tetsuka H, Ebina T, Nanjo H, Mizukami F, J. Mater. Chem., 17, 3545 (2007)
Yeun JH, Bang GS, Park BJ, Ham SK, Chang JH, J. Appl. Polym. Sci., 101, 591 (1999)
Ham M, Kim JC, Chang JH, Polym.(Korea), 37(2), 225 (2013)
Jang SW, Kim JC, Chang JH, Cellulose, 16, 445 (2009)
Yao KJ, Song M, Hourston DJ, Luo DZ, Polymer, 43(3), 1017 (2002)
Yang Y, Zhu ZK, Yin J, Wang XY, Qi ZE, Polymer, 40(15), 4407 (1999)
Ishii J, Takata A, Oami Y, Yokota R, Vladimirov L, Hasegawa M, Eur. Polym. J., 46, 681 (2010)
Choi IH, Chang JH, Polym.(Korea), 34(5), 480 (2010)
Pottiger MT, Coburn JC, Edman JR, J. Polym. Sci. B: Polym. Phys., 32(5), 825 (1994)
Yang CP, Su YY, Polymer, 46(15), 5778 (2005)
Sakaya T, Osaki N, J. Photopolym Sci. Technol., 19, 197 (2006)
Xu B, Zheng Q, Song YH, Shangguan Y, Polymer, 47(8), 2904 (2006)
Joly C, Smaihi M, Porcar L, Noble RD, Chem. Mater., 11, 2331 (1999)
Bharadwaj RK, Macromolecules, 34(26), 9189 (2001)
Huang JG, Cranford RJ, Matsuura T, Roy C, J. Membr. Sci., 215(1-2), 129 (2003)

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[2] Kawasaki K, Ebina T, Mizukami F, Tsuda H, Motegi K, Appl. Clay Sci., 48, 111 (2010)

[3] Manias E, Touny A, Wu L, Strawhecker K, Lu B, Chung TC, Chem. Mater., 13, 3516 (2001)

[4] Cendoya I, Lopez D, Alegria A, Mijangos C, J. Polym. Sci. B: Polym. Phys., 39(17), 1968 (2001)

[5] Legaly G, Smectitic Clays as Ionic Macromolecules, Elsevier, London, 1986, p 77.

[6] Suzuki F, Nakane K, Piao JS, J. Mater. Sci., 31(5), 1335 (1996)

[7] Chang JH, Jang TG, Ihn KJ, Lee WK, Sur GS, J. Appl. Polym. Sci., 90(12), 3208 (2003)

[8] Gilman JW, Appl. Clay Sci., 15, 31 (1999)

[9] Kojima Y, Usuki A, Kawasumi M, Okada A, J. Mater. Res., 8, 1185 (1993)

[10] LeBaron PC, Wang Z, Thomas JP, Appl. Clay Sci., 15, 11 (1999)

[11] Yano K, Usuki A, Karauchi T, Kamigaito O, J. Polym. Sci. A: Polym. Chem., 31, 2493 (1993)

[12] Messersmith PB, Giannelis EP, Chem. Mater., 5, 1064 (1993)

[13] Strawhecker KE, Manias E, Chem. Mater., 12, 2943 (2000)

[14] Jeon HJ, Youk JH, Yu WR, Macromol. Res., 18(5), 458 (2010)

[15] Nakane K, Yamashita T, Iwakura K, Suzuki F, J. Appl. Polym. Sci., 74(1), 133 (1999)

[16] Chuang WY, Young TH, Chiu WY, Lin CY, Polymer, 41(15), 5633 (2000)

[17] Huang S, Yang Z, Zhu H, Ren L, Tjiu WW, Liu T, Macromol. Res., 20(6), 568 (2012)

[18] Kokabi M, Sirousazar M, Hassan ZM, Eur. Polym. J., 43, 773 (2007)

[19] Zhen W, Lu C, Li C, Liang M, Appl. Clay Sci., 57, 64 (2012)

[20] Huang HD, Ren PG, Chen J, Zhang WQ, Ji X, Li ZM, J. Membr. Sci., 409-410, 156 (2012)

[21] Xu Y, Hong W, Bai H, Li C, Shi G, Carbon, 47, 3538 (2009)

[22] Gilman JW, Jackson CL, Morgan AB, Harris R, Chem. Mater., 12, 1866 (2000)

[23] Ebina T, Mizukami F, Adv. Mater., 19(18), 2450 (2007)

[24] Nam HJ, Ishii R, Ebina T, Mizukami F, Mater. Lett., 63, 54 (2009)

[25] Tetsuka H, Ebina T, Nanjo H, Mizukami F, J. Mater. Chem., 17, 3545 (2007)

[26] Yeun JH, Bang GS, Park BJ, Ham SK, Chang JH, J. Appl. Polym. Sci., 101, 591 (1999)

[27] Ham M, Kim JC, Chang JH, Polym.(Korea), 37(2), 225 (2013)

[28] Jang SW, Kim JC, Chang JH, Cellulose, 16, 445 (2009)

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[30] Yang Y, Zhu ZK, Yin J, Wang XY, Qi ZE, Polymer, 40(15), 4407 (1999)

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[32] Choi IH, Chang JH, Polym.(Korea), 34(5), 480 (2010)

[33] Pottiger MT, Coburn JC, Edman JR, J. Polym. Sci. B: Polym. Phys., 32(5), 825 (1994)

[34] Yang CP, Su YY, Polymer, 46(15), 5778 (2005)

[35] Sakaya T, Osaki N, J. Photopolym Sci. Technol., 19, 197 (2006)

[36] Xu B, Zheng Q, Song YH, Shangguan Y, Polymer, 47(8), 2904 (2006)

[37] Joly C, Smaihi M, Porcar L, Noble RD, Chem. Mater., 11, 2331 (1999)

[38] Bharadwaj RK, Macromolecules, 34(26), 9189 (2001)

[39] Huang JG, Cranford RJ, Matsuura T, Roy C, J. Membr. Sci., 215(1-2), 129 (2003)