Densities and ultrasonic velocities have been measured over the whole composition range for the binary liquid mixtures of dipropylene glycol monomethyl ether (mixture of isomers) {CH3(OC3H6)(2)OH}, dipropylene glycol monopropyl ether (mixture of isomers) {CH3(CH2)(2)(OC3H6)(2)OH}, and dipropylene glycol monobutyl ether (mixture of isomers){CH3(CH2)(3)(OC3H6)(2)OH} with alkyl acetates using an Anton Paar DSA 5000 density and speed sound analyzer in the temperature interval (288.15 to 308.15) K and atmospheric pressure. From these experimental data, excess molar volume, V-m(E) and deviations in isentropic compressibility, Delta kappa(S), have been calculated. The computed results of these quantities have been correlated using the Redlich-Kister polynomial equation to obtain the binary coefficients and standard deviations.