Journal of Chemical Physics, Vol.99, No.12, 9460-9464, 1993
Dynamics of Cs2 in the Large Spectral Bandwidth Stimulated Rayleigh-Wing Scattering
A theoretical model for the large bandwidth stimulated Rayleigh-wing scattering [D. Wang and G. Rivoire, J. Chem. Phys. 98, 9279 (1993)] has been built, based on the existence of a translational coherent collective movement driven by an intense optical field. Its rise and decay times deduced from the comparison with the experimental spectral observation are as short as 115 fs.