The vanadium pentoxide (V2O5)/graphene nanocomposite films have been synthesized by direct intercalation method using V2O5 sal and graphene. The structure of the films was investigated with X-Ray Diffraction (XRD). The electrochemical properties of the nanocomposite films were studied by cyclic voltammetry and chronoamperometry with the standard three-electrode configuration. The optical properties were characterized by UV-Visible spectrophotometer. The intercalation of graphene improves the stability and reversibility of the V2O5 xerogel films. The response rate of the V2O5/graphene nanocomposite films is enhanced. The optical modulatory range of the V2O5/graphene nanocomposite films is 1.5 times larger than that of V2O5 xerogel films. These results demonstrate that the nanocomposite films can be used potentially in fast switching electrochromic devices. (C) 2013 The Electrochemical Society. All rights reserved.