Journal of Chemical Physics, Vol.100, No.1, 733-735, 1994
Quantum-Mechanical Calculation of the Rate-Constant for the Reaction H+o2-)Oh+o
Rigorous three-dimensional quantum mechanical calculations have been carried out for the cumulative reaction probability of the titled reaction for total angular momentum, J=0. Higher values of J are included approximately, and the resulting thermal rate constant agrees well with experimental values for 800 less-than-or-equal-to T less-than-or-equal-to 3000 K.