화학공학소재연구정보센터
Journal of Chemical Physics, Vol.100, No.2, 1049-1057, 1994
Collision-Induced Dissociation of Co-N(+) (N=2-18) with Xe - Bond-Energies of Cationic and Neutral Cobalt Clusters, Dissociation Pathways, and Structures
The kinetic energy dependence bf collision-induced dissociation (CID) of Co-n(+) (n = 2-18) with xenon is studied by using a guided ion beam mass spectrometer. Examination of the general dissociation behavior over a broad collision energy range shows that cobalt cluster cations dissociate exclusively by loss of single atoms (cluster "evaporation"), with no evidence found for elimination of molecular cluster fragments. Bond dissociation energies for cobalt-cluster cations, Co-n(+). (n = 2-18), are determined from measurements of the CID thresholds. Bond energies for neutral cobalt clusters, Co-n (n = 4-18), are derived by combining these cationic bond energies with ionization energies for Co, from the literature. The dependence of binding energy on cluster size is similar to that observed for iron clusters, and inspires some speculation regarding cluster ion structures.