Journal of Chemical Physics, Vol.100, No.4, 3142-3148, 1994
Equation of State for Hard Convex Body-Fluids from the Equation of State of the Hard-Sphere Fluid
A simple and accurate equation of state for fluids of hard convex molecules is derived from the pressure equation and the equation of state of the hard sphere fluid. The equation of state provides theoretical support to some equations of state used in perturbation theories for real molecular liquids. The equation of state reproduces the simulation data with an accuracy comparable to that derived from density functional theory.
Keywords:SPHEROCYLINDER FLUIDS;PHASE-DIAGRAM;MONTE-CARLO;REVOLUTION;ELLIPSOIDS;MOLECULES;LIQUID;SYSTEM