Rheologica Acta, Vol.52, No.10-12, 927-937, 2013
Determination of flow activation energy at viscosity maximum for spherical and wormlike micelles of different lengths and flexibility
Steady shear rheological measurements were carried out on aqueous solutions containing 15 mM cetyltrimethylammonium bromide (CTABr) and a constant value of [MX] and temperature for MX = 2,3-; 2,4-; 2,5-; 2,6-; 3,4-; and 3,5-Cl(2)BzNa with Bz(-)representing C6H3CO2I.... Plots of zero shear viscosity (eta (0)) vs. [MX] at 35 A degrees C and 15 mM CTABr show the presence of single maximum and double maxima for MX = 2,3- and 3,5-Cl(2)BzNa, respectively. Turbidity data (absorbance at 600 nm vs. [MX]) coupled with eta (0)vs. [MX] data at 35 A degrees C reveal indirectly the presence of vesicles along with wormlike micelles (WM) at MX / CTABr > 0. 7 for MX = 3,5-Cl(2)BzNa. Temperature dependence of eta (0)in the vicinity of the viscosity maximum shows nonlinear and linear Arrhenius behavior, within the temperature range of 20-55 A degrees C, for MX = 2,3-; 2,4-; 2,5-; 3,4-; and 3,5-Cl(2)BzNa, respectively. The values of eta (0), (critical shear rate), and flow activation energy correlate with CTABr micellar binding constants of counterions.
Keywords:Rheology;Wormlike micelles;Counterion effect;Temperature effect;Micellar growth;Flow activation energy