화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.1, 37-45, January, 2014
DOI10.1016/j.jiec.2013.04.029  Export Citation
Comparative study of different systems for adsorption and catalytic oxidation of hexamine in industrial wastewaters
N. Zamani†, H.R. Rajabi1, M. Taghdiri2, A. Sohyl Fakhaei, and V. Vatanpour3
  • Department of Applied Chemistry, Faculty of Sciences, University of Semnan, Semnan, Iran
  • 1Chemistry Department, Yasouj University, Yasouj, 75918-74831, Iran
  • 2Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran
  • 3Faculty of Chemistry, Kharazmi (Tarbiat Moallem) University, Tehran, Iran
E-mail:
This work reports adsorption and catalytic oxidation process for degradation of hexamine (HMT)- containing industrial wastewater based on the reduction in total organic carbon. The studied systems include hydrogen peroxide, MCM-41, phosphotungstic acid (PTA)/MCM-41 embedded via impregnation method, PTA/H2O2 and PTA/MCM-41 embedded via impregnation or direct synthesis methods in the presence of hydrogen peroxide. The TOC results indicated that the system including PTA embedded within MCM-41 via direct synthetic method in the presence of H2O2 has a higher performance for degradation of HMT-containing wastewater. The total organic carbon for the mineralization of HMT was obtained to be 57%, under optimum conditions.
Keywords:Hexamine-containing waste;Advanced oxidation process;Phosphotungstic acid;Direct synthetic method;Kinetic study
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