화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.1, 145-152, January, 2014
DOI10.1016/j.jiec.2013.04.014  Export Citation
Influence of preparation method on the catalytic performances of Re2O7/SiO2-Al2O3 catalysts in the metathesis of ethylene and 2-pentene
Weena Phongsawat, Benjamas Netiworaruksa, Kongkiat Suriye1, Piyasan Praserthdam, and Joongjai Panpranot†
  • Center of Excellence on Catalysis and Catalytic Reaction Engineering, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok 10330, Thailand
  • 1SCG Chemicals Co., Ltd., 1 Siam-Cement Rd., Bang Sue, Bangkok 10800, Thailand
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The metathesis of ethylene and 2-pentene for propylene production was investigated over Re2O7/SiO2-Al2O3 catalysts. The SiO2-Al2O3 (50 wt% Al2O3) were obtained by co-precipitation, physical mixing, and sol-gel coating. The presence of isolated layers/grains g-Al2O3 either in bulk (physical mixing) or on the surface (sol-gel coating) resulted in isomerization-free metathesis. On the contrary, the Re2O7 catalysts supported on co-precipitated SiO2-Al2O3 or the direct synthesis showed both metathesis and doublebond shift isomerization activities and as a consequence, higher propylene yield was obtained via the secondary metathesis reaction. The catalytic properties were also correlated with the Al-atom rearrangements and the acidic characters/strengths.
Keywords:Metathesis;Isomerization;Propylene production;2-Pentene;Rhenium
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