NaIO4를 사용한 도파민-수식 폴리아스팔트아미드의 산화적 젤화

전영실; Quang Tri Bui; 안중현; 정동준; 김지흥; Young Sil Jeon; Quang Tri Bui; Jung Hyun An; Dong June Chung; Ji-Heung Kim

Polymer(Korea), Vol.38, No.1, 108-112, January, 2014

Export Citation

NaIO4를 사용한 도파민-수식 폴리아스팔트아미드의 산화적 젤화

Oxidative Gelation of Dopamine-modified Polyaspartamides by NaIO4

전영실, Quang Tri Bui, 안중현, 정동준 ¹, 김지흥 ^†

성균관대학교 화학공학부
¹성균관대학교 고분자공학과

Young Sil Jeon, Quang Tri Bui, Jung Hyun An, Dong June Chung¹, and Ji-Heung Kim^†

School of Chemical Engineering, Sungkyunkwan University, 300 Chunchun, Jangan, Suwon, Gyeonggi 440-746, Korea
¹Department of Polymer Science & Engineering, Sungkyunkwan University, 300 Chunchun, Jangan, Suwon, Gyeonggi 440-746, Korea

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초록

도파민 및 에틸렌디아민의 폴리숙신이미드(polysuccinimide) 와의 연속적인 개환 아미놀리시스 반응을 통해 카테콜및 1차 아민기를 곁가지에 함유한 접착성 폴리아스팔트아미드를 합성하고, 산화제로서 NaIO4를 사용한 상기 고분자 수용액의 산화적 젤화 반응을 관찰하였다. FTIR, UV-vis과 oscillatory rheometry를 이용하여 산화성 가교반응을 통한 젤형성을 규명하고, 제조된 젤의 수팽윤도, 열중량분석(TGA) 및 SEM 모폴로지를 조사하였다.

Novel adhesive polyaspartamides containing catechol and primary amine pendent groups were synthesized through successive ring-opening aminolysis reactions of dopamine (DOP) and ethylenediamine (EDA) with polysuccinimide (PSI). The oxidative gelation of aqueous dopamine-modified polyaspartamide was observed by adding NaIO4 as the oxidizing reagent. FTIR, UV-vis and oscillatory rheometry was used to elucidate the oxidative cross-linking toward gel formation. The prepared gel was characterized by the swelling degree, thermogravimetric analysis (TGA), and by scanning electronic microscopy (SEM).

Keywords:dopamine-modified;polyaspartamide;oxidative gelation;adhesive.

[References]

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Waite JH, Tanzer ML, Science, 212, 1038 (1981)
Lee HS, Dellatore SM, Miller WM, Messersmith PB, Science, 318, 426 (2007)
Waite JH, Qin XX, Biochemistry, 40, 2887 (2001)
Yu ME, Deming TJ, Macromolecules, 31(15), 4739 (1998)
Dalsin JL, Hu BH, Lee BP, Messersmith PB, J. Am. Chem. Soc., 125(14), 4253 (2003)
Fan XW, Lin LJ, Dalsin JL, Messersmith PB, J. Am. Chem. Soc., 127(45), 15843 (2005)
Lee BP, Dalsin JL, Messersmith PB, Biomacromolecules, 3(5), 1038 (2002)
Shao H, Bachus KN, Stewart RJ, Macromol. Biosci., 9, 464 (2009)
Brubaker CE, Kissler H, Wang LJ, Kaufman DB, Messersmith PB, Biomaterials, 31, 420 (2010)
Lee H, Lee Y, Statz AR, Rho J, Park TG, Messersmith PB, Adv. Mater., 20(9), 1619 (2008)
Yamada K, Chen TH, Kumar G, Vesnovsky O, Topoleski LDT, Payne GF, Biomacromolecules, 1(2), 252 (2000)
Ku SH, Ryu JK, Hong SK, Lee HS, Park CB, Biomaterials, 31, 2535 (2010)
Holowka EP, Deming TJ, Macromol. Biosci., 10, 496 (2010)
Moon JR, Kim JH, Polym. Int., 59, 630 (2010)
Moon JR, Kim MW, Kim DJ, Jeong JH, Kim JH, Colloid Polym. Sci., 289, 63 (2010)
Moon JR, Kim JH, Macromol. Res., 16(6), 489 (2008)
Moon JR, Park YH, Kim JH, J. Appl. Polym. Sci., 111(2), 998 (2009)
Park JH, Moon JR, Hong KH, Kim JH, J. Polym. Res., 18, 273 (2011)
Kim SI, Son CM, Jeon YS, Kim JH, Bull. Korean Chem. Soc., 30, 3025 (2009)
An JH, Huynh NT, Jeon YS, Kim JH, Polym. Int., 60, 1581 (2011)

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[2] Waite JH, Tanzer ML, Science, 212, 1038 (1981)

[3] Lee HS, Dellatore SM, Miller WM, Messersmith PB, Science, 318, 426 (2007)

[4] Waite JH, Qin XX, Biochemistry, 40, 2887 (2001)

[5] Yu ME, Deming TJ, Macromolecules, 31(15), 4739 (1998)

[6] Dalsin JL, Hu BH, Lee BP, Messersmith PB, J. Am. Chem. Soc., 125(14), 4253 (2003)

[7] Fan XW, Lin LJ, Dalsin JL, Messersmith PB, J. Am. Chem. Soc., 127(45), 15843 (2005)

[8] Lee BP, Dalsin JL, Messersmith PB, Biomacromolecules, 3(5), 1038 (2002)

[9] Shao H, Bachus KN, Stewart RJ, Macromol. Biosci., 9, 464 (2009)

[10] Brubaker CE, Kissler H, Wang LJ, Kaufman DB, Messersmith PB, Biomaterials, 31, 420 (2010)

[11] Lee H, Lee Y, Statz AR, Rho J, Park TG, Messersmith PB, Adv. Mater., 20(9), 1619 (2008)

[12] Yamada K, Chen TH, Kumar G, Vesnovsky O, Topoleski LDT, Payne GF, Biomacromolecules, 1(2), 252 (2000)

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[14] Holowka EP, Deming TJ, Macromol. Biosci., 10, 496 (2010)

[15] Moon JR, Kim JH, Polym. Int., 59, 630 (2010)

[16] Moon JR, Kim MW, Kim DJ, Jeong JH, Kim JH, Colloid Polym. Sci., 289, 63 (2010)

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[18] Moon JR, Park YH, Kim JH, J. Appl. Polym. Sci., 111(2), 998 (2009)

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[20] Kim SI, Son CM, Jeon YS, Kim JH, Bull. Korean Chem. Soc., 30, 3025 (2009)

[21] An JH, Huynh NT, Jeon YS, Kim JH, Polym. Int., 60, 1581 (2011)