Direct synthesis of bi-modal porous structure MCM-41 and its application in CO2 capturing through amine-grafting

Mohsen Gholami; Mohammad Reza Talaie; Seyed Foad Aghamiri

Korean Journal of Chemical Engineering, Vol.31, No.2, 322-326, February, 2014

DOI10.1007/s11814-013-0230-5 Export Citation

Direct synthesis of bi-modal porous structure MCM-41 and its application in CO2 capturing through amine-grafting

Mohsen Gholami^†, Mohammad Reza Talaie, and Seyed Foad Aghamiri

Department of Chemical Engineering, College of Engineering, University of Isfahan, P. O. Box 81746-73441, Isfahan, Iran

E-mail:

A bi-modal porous structure MCM-41 (BPS-MCM-41) was synthesized and functionalized by 3-[2-(2-Aminoethylamino)ethylamino]propyltrimethoxysilane (TRI); also, its performance in amine grafting and CO2 capturing was compared with that of pore-expanded MCM-41 [1]. To create larger pores beside the mesoporous structure of MCM-41, carbon black nanoparticles were used as the solid template. Characterizing the BPS-MCM-41 using the BET and BJH techniques resulted in the surface reduction of 29.3 percent and volume increase of 68.46 percent. The pore size distribution showed two peaks: a narrow peak at 2.24 nm diameter, which belonged to micelles, and a wide one at about 50 nm due to the presence of used nanoparticles. The functionalization confirmed that BPS-MCM-41 is capable of accommodating a large quantity of amine groups. The CO2 adsorption measurement indicated that internal volume of the adsorbent was a critical factor affecting the adsorption capacity of the amine grafted adsorbents.

Keywords:Amine Grafted Adsorbent;BPS-MCM-41;CO2 Capture;Hierarchical Structure;Amine Loading

[References]

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[2] Kohl AL, Nielsen RB, in “Gas Purification (Fifth Edition)”, Gulf Professional Publishing, Houston, 40 (1997)

[3] Meisen A, Shuai X, Energy Convers. Manage., 38, Supplement, S37 (1997)

[4] Choi S, Drese JH, Jones CW, ChemSusChem, 2, 796 (2009)

[5] Carter JW, Husain H, Chem. Eng. Sci., 29, 267 (1974)

[6] Shen CM, Worek WM, Int. J. Heat Mass Transf., 37(14), 2123 (1994)

[7] Mohamadinejad H, Knox JC, Smith JE, Sep. Sci. Technol., 35, 1 (2000)

[8] Rege SU, Yang RT, Qian KY, Buzanowski MA, Chem. Eng. Sci., 56(8), 2745 (2001)

[9] Konduru N, Lindner P, Assaf-Anad NM, AIChE J., 53(12), 3137 (2007)

[10] Li G, Xiao P, Webley P, Zhang J, Singh R, Marshall M, Adsorption, 14, 415 (2008)

[11] Wang Y, LeVan MD, J. Chem. Eng. Data, 55, 3189 (2009)

[12] Li G, Xiao P, Webley PA, Zhang J, Singh R, Energy Procedia, 1, 1123 (2009)

[13] Li G, Xiao P, Webley P, Langmuir, 25(18), 10666 (2009)

[14] Tlili N, Grevillot G, Vallieres C, Int. J. Greenhouse Gas Control, 3, 519 (2009)

[15] Wang Y, Levan MD, J. Chem. Eng. Data, 55(9), 3189 (2010)

[16] Hogendoorn JA, Vanswaaij WP, Versteeg GF, Chem. Eng. Sci., 49(20), 3421 (1994)

[17] Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, J. Am. Chem. Soc., 114, 10834 (1992)

[18] Das DD, Harlick PJE, Sayari A, Catal. Commun., 8, 829 (2007)

[19] Loganathan S, Tikmani M, Ghoshal AK, Langmuir, 29(10), 3491 (2013)

[20] Jana S, Mochizuki A, Namba S, Catal. Surv. Asia, 8, 1 (2004)

[21] Hornacek M, Hudec P, Smieskova A, Chem. Pap., 63, 689 (2009)

[22] Kierys A, Buda W, Goworek J, J. Porous Mater., 17, 669 (2010)

[23] Mizutani M, Yamada Y, Yano K, Chem. Commun., 1172 (2007)

[24] Stein A, Micropor. Mesopor. Mater., 44-45, 227 (2001)

[25] Danumah C, Vaudreuil S, Bonneviot L, Bousmina M, Giasson S, Kaliaguine S, Micropor. Mesopor. Mater., 44-45, 241 (2001)

[26] Chen C, Yang ST, Ahn WS, Ryoo R, Chem. Commun., 3627 (2009)

[27] Du J, Lai X, Yang N, Zhai J, Kisailus D, Su F, Wang D, Jiang L, ACS Nano, 5, 590 (2011)

[28] Yang XY, Li Y, Lemaire A, Yu JG, Su BL, Pure Appl. Chem., 81, 2265 (2009)

[29] Lei Q, Zhao T, Li F, Wang Y, Hou L, J. Porous Mater., 15, 643 (2008)

[30] Franchi RS, Harlick PJE, Sayari A, Ind. Eng. Chem. Res., 44(21), 8007 (2005)

[31] Harlick PJE, Sayari A, Ind. Eng. Chem. Res., 46, 446 (2006)

[32] Belmabkhout Y, Sayari A, Adsorption, 15, 318 (2009)

[33] Franchi R, Harlick PJE, Sayari A, Abdelhamid S, Mietek J, in “Studies in Surface Science and Catalysis”, Elsevier, 156, 879 (2005)

[34] Serna-Guerrero R, Belmabkhout Y, Sayari A, Chem. Eng. Sci., 65(14), 4166 (2010)

[35] Heydari-Gorji A, Belmabkhout Y, Sayari A, Langmuir, 27, 124111 (2010)

[36] Serna-Guerrero R, Belmabkhout Y, Sayari A, Adsorption, 16, 567 (2010)

[37] Qi G, Wang Y, Estevez L, Duan X, Anako N, Park AHA, Li W, Jones CW, Giannelis EP, Energy Environ. Sci., 4, 444 (2011)

[38] Kumar D, Schumacher K, du Fresne von Hohenesche C, Grun M, Unger KK, Colloids Surf., A, 187-188, 109 (2001)

[39] Xu X, Song C, Andrsen JM, Miller BG, Scaroni AW, Micropor. Mesopor. Mater., 62, 29 (2003)

[40] Vartuli JC, Roth WJ, Beck JS, McCullen SB, Kresge CT, in “Synthesis”, Springer Berlin Heidelberg, 1, 97 (1998)

[41] Wang Y, Levan MD, J. Chem. Eng. Data, 54(10), 2839 (2009)