High efficient adsorption of gold ions onto the novel functional composite silica microspheres encapsulated by organophosphonated polystyrene

Ping Yin; Mingyu Xu; Wei Liu, Rongjun Qu; Rongjun Qu; Xiguang Liu; Qiang Xu

Journal of Industrial and Engineering Chemistry, Vol.20, No.2, 379-390, March, 2014

DOI10.1016/j.jiec.2013.04.032 Export Citation

High efficient adsorption of gold ions onto the novel functional composite silica microspheres encapsulated by organophosphonated polystyrene

Ping Yin^†, Mingyu Xu, Wei Liu, Rongjun Qu, Rongjun Qu^†, Xiguang Liu, and Qiang Xu

School of Chemistry and Materials Science, Ludong University, Yantai 264025, PR China

E-mail:,

The novel functional composite silica microspheres encapsulated by organophosphonated polystyrene (SG-PS-N-P) has been successfully synthesized. SG.PS.N.P was employed to adsorb Au(III) from simulated wastewater, and it exhibited excellent performance, and the maximum adsorption capacity was 980.39 mg/g at 35 ℃. The adsorption process optimization was performed using response surface methodology (RSM), and the analysis of variance(ANOVA) of the quadratic model demonstrated that the model was highly significant. Moreover, the regeneration capacities of SG-PS-N-P were investigated, and it has been found that the adsorption capability remains high after several cycles of adsorption-desorption.

Keywords:Composite;Functionalization of polymers;Silica;Encapsulation;Au(III) adsorption;Response surface methodology

[References]

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Do KM, Yuvaraj H, Woo MH, Kim HG, Jeong ED, Johnson KP, Lim KT, Colloid Polym. Sci., 286, 1343 (2008)
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Ding DG, Yin MC, Lu HJ, Fan YT, Hou HW, Wang YT, J. Solid State Chem., 179, 747 (2006)
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Qu RJ, Wang MG, Sun CM, Zhang Y, Ji CA, Chen H, Meng YF, Yin P, Appl. Surf. Sci., 255(5), 3361 (2008)
Ho YS, Carbon, 42, 2115 (2004)
Sari A, Tuzen M, Soylak M, J. Hazard. Mater., 144(1-2), 41 (2007)
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Sari A, Tuzen M, Citak D, Soylak M, J. Hazard. Mater., 148(1-2), 387 (2007)
Sari A, Citak D, Tuzen M, Chem. Eng. J., 162(2), 521 (2010)
Fujiwara K, Ramesh A, Maki T, Hasegawa H, Ueda K, J. Hazard. Mater., 146(1-2), 39 (2007)
Gamez G, Gardea-Torresdey JL, Tiemann KJ, Parsons J, Dokken K, Yacaman MJ, Adv. Environ. Res., 7, 563 (2003)
Tian YA, Yin P, Qu RJ, Wang CH, Zheng HG, Yu ZX, Chem. Eng. J., 162(2), 573 (2010)
Jing XB, Cao YR, Zhang XY, Wang DS, Wu XZ, Xu H, Desalination, 269(1-3), 120 (2011)
Khuri AI, Cornell JA, Response Surface: Design and Analysis, 1 (1987)
Yalvac can M, Kaya Y, Faruk Algur O, Biomed. Tech., 97, 1761 (2006)

[Referenced By]

[1] Renuka RG, Balasubramanian K, J. Hazard. Mater., 217-218, 447 (2012)

[2] Lam KF, Fong CM, Yeung KL, Mckay G, Chem. Eng. J., 145(2), 185 (2008)

[3] Olgun A, Atar N, J. Ind. Eng. Chem., 18(5), 1751 (2012)

[4] Perez-Quintanilla D, del Hierro I, Fajardo M, Sierra I, J. Hazard. Mater., 134(1-3), 245 (2006)

[5] Chen CM, Chung MH, Hsieh TE, Liu MO, Lin JL, Chu WP, Tang RM, Tsai YS, Juang FS, Compos. Sci. Technol., 68, 3041 (2008)

[6] Liu P, Su ZX, Mater. Chem. Phys., 94(2-3), 412 (2005)

[7] Li YS, Li B, Han NY, Xu BJ, J. Chromatogr. A, 1021, 186 (2003)

[8] Do KM, Yuvaraj H, Woo MH, Kim HG, Jeong ED, Johnson KP, Lim KT, Colloid Polym. Sci., 286, 1343 (2008)

[9] Liu CH, Pan CY, Polymer, 48(13), 3679 (2007)

[10] Ding DG, Yin MC, Lu HJ, Fan YT, Hou HW, Wang YT, J. Solid State Chem., 179, 747 (2006)

[11] Ghorbani F, Younesi H, Ghasempouri SM, Zinatizadeh AA, Amini M, Daneshi A, Chem. Eng. J., 145(2), 267 (2008)

[12] Frisch MJ, Trucks GW, Schlegel HB, et al., Gaussian 03, Gaussian, Inc., Pittsburgh, PA, 2003. (2003)

[13] Latham K, White KF, Szpakolski KB, Rix CJ, White JM, Inorg. Chim. Acta., 362, 1872 (2009)

[14] Machado RSA, Da Fonseca MG, Arakaki LNH, Espinola JP, Oliveira SF, Talanta, 63, 317 (2004)

[15] Qu RJ, Wang MG, Sun CM, Zhang Y, Ji CA, Chen H, Meng YF, Yin P, Appl. Surf. Sci., 255(5), 3361 (2008)

[16] Ho YS, Carbon, 42, 2115 (2004)

[17] Sari A, Tuzen M, Soylak M, J. Hazard. Mater., 144(1-2), 41 (2007)

[18] Sari A, Tuzen M, Desalination, 249(1), 260 (2009)

[19] Sari A, Tuzen M, Citak D, Soylak M, J. Hazard. Mater., 148(1-2), 387 (2007)

[20] Sari A, Citak D, Tuzen M, Chem. Eng. J., 162(2), 521 (2010)

[21] Fujiwara K, Ramesh A, Maki T, Hasegawa H, Ueda K, J. Hazard. Mater., 146(1-2), 39 (2007)

[22] Gamez G, Gardea-Torresdey JL, Tiemann KJ, Parsons J, Dokken K, Yacaman MJ, Adv. Environ. Res., 7, 563 (2003)

[23] Tian YA, Yin P, Qu RJ, Wang CH, Zheng HG, Yu ZX, Chem. Eng. J., 162(2), 573 (2010)

[24] Jing XB, Cao YR, Zhang XY, Wang DS, Wu XZ, Xu H, Desalination, 269(1-3), 120 (2011)

[25] Khuri AI, Cornell JA, Response Surface: Design and Analysis, 1 (1987)

[26] Yalvac can M, Kaya Y, Faruk Algur O, Biomed. Tech., 97, 1761 (2006)