화학공학소재연구정보센터
Journal of Chemical Physics, Vol.100, No.9, 6665-6671, 1994
An Analytical Analysis of the Square-Well Fluid Behaviors
Analytical expressions of the Helmholtz free energy, internal energy, and compressibility for the square-well fluid are developed from the first-order solution of the mean spherical approximation with further application of the Hilbert transform proposed previously. The developed expressions, including that of the first-order radial distribution function, are satisfactorily compared with the Monte Carlo simulation data available in the literature.