Journal of Industrial and Engineering Chemistry, Vol.20, No.3, 916-924, May, 2014
Adsorption behavior of estrogenic compounds on carbon nanotubes from aqueous solutions: Kinetic and thermodynamic studies
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In this study different estrogenic compounds, estrone (E1), 17β-estradiol (E2), and 17α-ethinylestradiol (EE2), were removed from the model and real solution by the newly emerged multi-walled carbon nanotubes. The effects of different factors which affect the removal process were studied and optimized for efficient removal. The kinetics of E1, E2, and EE2 adsorption on MWCNTs were analyzed using different kinetic models and the results showed that the removal was mainly a pseudo-second-order process. The thermodynamic study showed the spontaneity and exothermic nature of the removal process, with negative entropy.
- Gillesby B, Zacharewski T, Environ. Toxicol. Chem., 17, 3 (1998)
- Mozaz SR, Lopez de Alda M, Barcelo D, J. Chromatogr. A, 1045, 85 (2004)
- Robert FC, Rominder PSS, Fu HX, Water Environ. Res., 79, 969 (2007)
- Johnson A, Sumpter J, Environ. Sci. Technol., 35, 4697 (2001)
- Zhou JL, Liu R, Wilding A, Hibberd A, Environ. Sci. Technol., 41, 206 (2007)
- Maniero MG, Bila DM, Dezotti M, Sci. Total Environ., 407, 105 (2008)
- Lee S, Lee JW, Kim S, Park PK, Kim JH, Lee CH, J. Membr. Sci., 326(1), 84 (2009)
- Heo J, Flora JRV, Her N, Park YG, Cho J, Son A, Yoon Y, Sep. Purif. Technol., 90, 39 (2012)
- Bistan M, Tisˇler T, Pintar A, Catal. Commun., 22, 74 (2012)
- Pereira R, de Alda M, Joglar J, Daniel LA, Barcelo D, Chemosphere, 84, 1535 (2011)
- Pereira R, Postigo C, de Alda M, Daniel L, Barcelo D, Chemosphere, 82, 789 (2011)
- Rossner A, Snyder SA, Knappe DRU, Water Res., 43, 3787 (2009)
- Koc I, Baydemir G, Bayram E, Yavuz H, Denizli A, J. Hazard. Mater., 192(3), 1819 (2011)
- Joseph L, Heo J, Park YG, Flora JRV, Yoon Y, Desalination, 281, 68 (2011)
- Kumar AK, Mohan SV, Sep. Purif. Technol., 87, 22 (2012)
- Sirivisoot S, Webster TJ, Compre. Biomater., 5, 303 (2011)
- Orinakova R, Orinak A, Fuel, 90(11), 3123 (2011)
- Gomez-Gualdro´ n DA, Burgos JC, Yu J, Balbuena PB, Prog. Molecular. Trans. Sci., 104, 175 (2011)
- Ahn CH, Baek Y, Lee C, Kim SO, Kim S, Lee S, Kim SH, Bae SS, Park J, Yoon J, J. Ind. Eng. Chem., 18(5), 1551 (2012)
- Pan L, Pei X, He R, Wan Q, Wang J, Colloids Surf. B: Biointerfaces, 93, 226 (2012)
- Bayazit SS, Inci I, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.03.023. (2013)
- Salam MA, Kosa SA, Zhrani GA, Comp. Ren. Chim., 15, 398 (2012)
- Prlainovic NZ, Bezbradica DI, Knezˇevic´-Jugovic ZD, Stevanovic SI, Ivic´ MLA, Uskokovic´ PS, Mijin DZ, J. Ind. Eng. Chem., 19(1), 279 (2013)
- Liao Q, Sun J, Gao L, Colloids Surf. A: Physicochem. Eng. Asp., 312, 160 (2008)
- Zhang L, Song XY, Liu XY, Yang LJ, Pan F, Lv JN, Chem. Eng. J., 178, 26 (2011)
- Al-Johani H, Salam MA, J. Colloid Interface Sci., 360(2), 760 (2011)
- Salam MA, Burk R, Water Air Soil Pollut., 210, 101 (2010)
- Ren XM, Chen CL, Nagatsu M, Wang XK, Chem. Eng. J., 170(2-3), 395 (2011)
- Gao R, Su X, He X, Zhang Y, Talanta, 83, 757 (2011)
- Salam MA, Makki MSI, Abdelaal MY, J. Alloy. Compd., 509, 2582 (2011)
- Ying G, Kookana RS, Ru Y, Environ. Int., 28, 545 (2002)
- Pan B, Lin DH, Mashayekhi H, Xing BS, Environ. Sci. Technol., 42, 5480 (2008)
- Dalal RC, Comm. Soil Sci. Plant Anal., 5, 531 (1974)
- Lagergren S, Zur theorie der sogenannten adsorption gel.oster Stoffe - About the theory of so-called adsorption of soluble substances. Kungliga Svenska Vetenskapsakademiens. Handlingar, Band 24, 1898, p. 1. (1898)
- Rudzinski W, Plazinski W, Adsorption, 15, 181 (2009)
- Ren Y, Nakano K, Nomura M, Chiba N, Nishimura O, Water Res., 41, 2341 (2007)
- Ifelebuegu AO, Theophilus SC, Bateman MJ, Int. J. Environ. Sci. Tech., 7, 617 (2010)
- Liu M, Lai EPC, Yang Y, Int. J. Res. Rev. Appl. Sci., 11, 67 (2012)
- Chien SH, Clayton WR, Soil Sci. Soc. Am. J., 44, 265 (1980)
- Weber WJ, Morris JC, J. Sanitary Eng. Div, Am. Soc. Civil Eng., 89, 31 (1963)
- Boyd GE, Adamson AW, Myers LS, J. Am. Chem. Soc., 69, 2836 (1947)
- Bulut E, Ozacar M, Sengil IA, Microporous Mesoporous Mater., 115, 234 (2008)
- Yang XY, Al-Duri B, J. Colloid Interface Sci., 287(1), 25 (2005)
- Kumar AK, Mohan SV, Sarma PN, J. Hazard. Mater., 164(2-3), 820 (2009)
- Chang S, Waite TD, Schafer AI, Fane AG, Desalination, 146(1-3), 381 (2002)