Nano-SiO2/fluorinated waterborne polyurethane nanocomposite adhesive for laminated films

Heqing Fu; Caibin Yan; Wei Zhou; Hong Huang

Journal of Industrial and Engineering Chemistry, Vol.20, No.4, 1623-1632, July, 2014

DOI10.1016/j.jiec.2013.08.009 Export Citation

Nano-SiO2/fluorinated waterborne polyurethane nanocomposite adhesive for laminated films

Heqing Fu^†, Caibin Yan, Wei Zhou, and Hong Huang

School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China

E-mail:

High performance nanocomposite adhesives used for the laminated films were synthesized. The effects of nano-SiO2 and HFBMA contents on the properties of SiO2/FWPU nanocomposite adhesive were investigated by the static contact angle measurement, X-ray photoelectron spectroscopy, atomic force microscopy, thermogravimetric analysis and tensile test machine. It proved that the wetting behavior, water resistance and thermal stability of nanocomposite adhesive had effect on the adhesion of the nanocomposite adhesive for low surface energy materials. And an empirical equation, T = e^(32.04) × γL^(-8.08) × γS^(0.45), revealing the relationship among adhesion strength (T), surface tension of adhesive (γL) and the surface energy of adhered substrate (γS)was obtained.

Keywords:Empirical model;Waterborne polyurethane;Nanocomposite adhesive;Laminated films;Adhesion strength

[References]

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[1] Aznar M, Vera P, Canellas E, Nerin C, Mercea P, Stormer A, J. Mater. Chem., 21, 4358 (2011)

[2] Mareri P, Bastide S, Binda N, Crespy A, Compos. Sci. Technol., 58, 747 (1998)

[3] Kalapat N, Amornsakchai T, Surf. Coat. Technol., 207, 594 (2012)

[4] Haridoss S, Perlman MM, J. Appl. Phys., 55, 1332 (1984)

[5] Viraneva A, Yovcheva T, Hristov M, Mekishev G, IEEE Trans. Dielectr. Electr. Insul., 19, 1132 (2012)

[6] Hammoud AN, Laghari JR, Krishnakumar B, IEEE Trans. Nucl. Sci., 35, 1026 (1988)

[7] Cygan SP, Laghari JR, IEEE Trans. Nucl. Sci., 38, 906 (1991)

[8] Abdul-Kader AM, El-Gendy YA, Al-Rashdy AA, Radiat. Phys. Chem., 81, 798 (2012)

[9] Lee DK, Tsai HB, Wang HH, Tsai RS, J. Appl. Polym. Sci., 94(4), 1723 (2004)

[10] Zhang JL, Wu DM, Yang DY, Qiu FX, J. Polym. Environ., 18, 128 (2010)

[11] Wang L, Shen YD, Lai XJ, Li ZJ, J. Appl. Polym. Sci., 119(6), 3521 (2011)

[12] Jena KK, Sahoo S, Narayan R, Aminabhavi TM, Raju K, Polym. Int., 60, 1504 (2011)

[13] Rostami M, Mohseni M, Ranjbar Z, Int. J. Adhes. Adhes., 34, 24 (2012)

[14] Petrovic ZS, Cho YJ, Javni I, Magonov S, Yerina N, Schaefer DW, Ilavsky J, Waddon A, Polymer, 45(12), 4285 (2004)

[15] Rostami M, Mohseni M, Ranjbar Z, Pigment Resin Technol., 40, 363 (2011)

[16] Li XH, Cao Z, Zhang ZJ, Dang HX, Appl. Surf. Sci., 252(22), 7856 (2006)

[17] Li ZW, Zhu YF, Appl. Surf. Sci., 211(1-4), 315 (2003)

[18] Takai C, Fuji M, Takahashi M, Colloids Surf. A: Physicochem. Eng. Asp., 292, 79 (2007)

[19] Hwang HD, Kim HJ, J. Colloid Interface Sci., 362(2), 274 (2011)

[20] Castelvetro V, Ciardelli F, Francini G, Baglioni P, Macromol. Mater. Eng., 278, 6 (2000)

[21] Levine F, Scala JL, Kosik W, Prog. Org. Coat., 69, 63 (2010)

[22] Bonk HW, Saidanpoli AA, Ulrich HJ, Elastoplast, 3, 157 (1971)

[23] Mark HF, Debye PJ, in: Weiss P (Ed.), Adhesion and Cohesion, Elsevier, New York, 1962, p. 240.

[24] Grimeley H, Aspects Adhesion, 7, 11 (1973)

[25] Eley DD, Adhesion, London Oxford University Press, Oxford, UK, 1961.

[26] Tyczkowski J, Krawczyk-Klys I, Kuberski S, Makowski P, Eur. Polym. J., 46, 767 (2010)

[27] Li M, Zheng Z, Liu S, Su Y, Wei W, Wang X, Int. J. Adhes. Adhes., 31, 565 (2011)

[28] Mishra D, Sinha VK, Int. J. Adhes. Adhes., 30, 47 (2010)

[29] Gao F, Ku B, Huang SQ, J. Appl. Polym. Sci., 122(2), 798 (2011)

[30] Geerken MJ, Lammertink RGH, Wessling M, Colloids Surf. A: Physicochem. Eng. Asp., 292, 224 (2007)

[31] Waghmare PR, Mitra SK, Langmuir, 26(22), 17082 (2010)

[32] Jiang L, Chen YL, Hu CP, J. Coat. Technol., 4, 59 (2007)

[33] Yeh JM, Yao CT, Hsieh CF, Yang HC, Wu CP, Eur. Polym. J., 44, 2777 (2008)

[34] Patel A, Patel C, Patel MG, Patel M, Dighe A, Prog. Org. Coat., 67, 255 (2010)

[35] Cervantes-Uc JM, Espinosa JIM, Cauich-Rodriguez JV, Avila-Ortega A, Vazquez-Torres H, Marcos-Fernandez A, Roman JS, Polym. Degrad. Stabil., 94, 1666 (2009)

[36] Zhang Y, Zhang PP, Chen XX, Wu ZS, Wu QX, Ind. Eng. Chem. Res., 50(4), 2111 (2011)