Synthesis and characterization of bimodal silver nanoparticles by using semi-batch method

Pradip B. Sarawade; Sang Min Kim; Ki Do Kim; Hee Taik Kim

Journal of Industrial and Engineering Chemistry, Vol.20, No.4, 1830-1833, July, 2014

DOI10.1016/j.jiec.2013.08.038 Export Citation

Synthesis and characterization of bimodal silver nanoparticles by using semi-batch method

Pradip B. Sarawade, Sang Min Kim¹, Ki Do Kim , and Hee Taik Kim^†

Department of Chemical Engineering, Hanyang University, 1271 Sa 3-dong, Sangnok-gu, Ansan-si, Gyeonggi-do 426-791, Republic of Korea
¹R&D Center, UNID Co. Ltd, Inchenon, Gyeonggi-do 402-041, Republic of Korea

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Synthesis of silver nanoparticles stabilized by myristic acids is reported. Bimodal shape of silver nanoparticles was formed by feed rate control using semi-batch method. The synthesized nanoparticles were re-dispersible in solution such as α-terpineol. The α-terpineol solution of these nanoparticles exhibited a surface plasmon resonance in the range around 430 nm. This broad absorption band depicted that the silver nanoparticles have an enhanced stability with increasing chain length of the fatty acid. The size of nanoparticles was influenced by the experimental conditions such as temperature, feed rate and reaction time. The nanoparticles were characterized by TEM, UV and XRD analyses.

Keywords:Silver nanoparticles;Monodisperse;Bimodal shape;Ligand;Thermal conductivity

[References]

Feldheim DL, Foss CA, (Eds.), Metal Nanoparticles: Synthesis, Characterization and Applications, Marcel Dekker, New York, 2002.
Gates BC, Chem. Rev., 95(3), 511 (1995)
Jana NR, Sau TK, Pal T, J. Phys. Chem. B, 103(1), 115 (1999)
Lin JC, Wang CY, Mater. Phys. Chem., 45, 136 (1996)
Taleb A, Petit C, Pileni MP, J. Phys. Chem., 102, 2214 (1998)
Petit C, Taleb A, Pileni MP, Adv. Mater., 10(3), 259 (1998)
Khanna PK, Kulkarni D, Rupinder, Beri K, J. Nanopart. Res., 10, 1059 (2008)
Shim IK, Lee YI, Lee KJ, Joung J, Mater. Chem. Phys., 110(2-3), 316 (2008)
Yamamoto M, Nakamoto M, J. Mater. Chem., 13, 2065 (2003)
Hirai H, Nakao Y, Toshima N, Chem. Lett., 905 (1976)
Delcourt MO, Keghouche N, Belloni J, Nouv. J. Chim., 7, 131 (1983)
Walker CH, St John JV, Wisian-Neilson P, J. Am. Chem. Soc., 123(16), 3846 (2001)
Schmid G, Lehnert A, Angew. Chem.-Int. Edit., 28, 780 (1989)
Green M, O’Brien P, Chem. Commun., 183 (2000)
Sarathy KV, Kulkarni GU, Rao CNR, Chem. Commun., 537 (1997)
The silver myristate.amine adduct, [Ag(n-C8H17NH2)2].[C13H27CO2], was isolated by adding ether to the reaction solution of silver myristate and n-octylamine. IR(KBr pellet): nCLO 1562, nC.O, 1428 cm21 (cf. silver myristate, nCLO 1703 cm21). GC/MS: m/z 228 (C13H27CO2H), 129 (n-C8H17NH2). Anal. Calcd for C30H65N2AgO2: C, 60.69; H, 11.04; N, 4.72%. Found: C, 59.93; H, 11.33; N, 4.69%.
Nakamoto K (Ed.), Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley & Sons, New York, 1985.
Nakamoto M, Yamamoto M, Chem. Commun., 452 (2003)
Rao CRK, Trivedi DC, Mater. Chem. Phys., 99(2-3), 354 (2006)

[Referenced By]

[Related Articles]

[1] Feldheim DL, Foss CA, (Eds.), Metal Nanoparticles: Synthesis, Characterization and Applications, Marcel Dekker, New York, 2002.

[2] Gates BC, Chem. Rev., 95(3), 511 (1995)

[3] Jana NR, Sau TK, Pal T, J. Phys. Chem. B, 103(1), 115 (1999)

[4] Lin JC, Wang CY, Mater. Phys. Chem., 45, 136 (1996)

[5] Taleb A, Petit C, Pileni MP, J. Phys. Chem., 102, 2214 (1998)

[6] Petit C, Taleb A, Pileni MP, Adv. Mater., 10(3), 259 (1998)

[7] Khanna PK, Kulkarni D, Rupinder, Beri K, J. Nanopart. Res., 10, 1059 (2008)

[8] Shim IK, Lee YI, Lee KJ, Joung J, Mater. Chem. Phys., 110(2-3), 316 (2008)

[9] Yamamoto M, Nakamoto M, J. Mater. Chem., 13, 2065 (2003)

[10] Hirai H, Nakao Y, Toshima N, Chem. Lett., 905 (1976)

[11] Delcourt MO, Keghouche N, Belloni J, Nouv. J. Chim., 7, 131 (1983)

[12] Walker CH, St John JV, Wisian-Neilson P, J. Am. Chem. Soc., 123(16), 3846 (2001)

[13] Schmid G, Lehnert A, Angew. Chem.-Int. Edit., 28, 780 (1989)

[14] Green M, O’Brien P, Chem. Commun., 183 (2000)

[15] Sarathy KV, Kulkarni GU, Rao CNR, Chem. Commun., 537 (1997)

[16] The silver myristate.amine adduct, [Ag(n-C8H17NH2)2].[C13H27CO2], was isolated by adding ether to the reaction solution of silver myristate and n-octylamine. IR(KBr pellet): nCLO 1562, nC.O, 1428 cm21 (cf. silver myristate, nCLO 1703 cm21). GC/MS: m/z 228 (C13H27CO2H), 129 (n-C8H17NH2). Anal. Calcd for C30H65N2AgO2: C, 60.69; H, 11.04; N, 4.72%. Found: C, 59.93; H, 11.33; N, 4.69%.

[17] Nakamoto K (Ed.), Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley & Sons, New York, 1985.

[18] Nakamoto M, Yamamoto M, Chem. Commun., 452 (2003)

[19] Rao CRK, Trivedi DC, Mater. Chem. Phys., 99(2-3), 354 (2006)