Applied poly(2-methoxy aniline) Sn(II)silicate carbon nanotubes composite: Synthesis, characterization, structure-property relationships and applications

Anish Khan; Aftab Aslam Parwaz Khan; Abdullah M. Asiri; Malik Abdul Rub; Naved Azum; Sher Bahadar Khan; Hadi M. Marwani

Journal of Industrial and Engineering Chemistry, Vol.20, No.4, 2301-2309, July, 2014

DOI10.1016/j.jiec.2013.10.005 Export Citation

Applied poly(2-methoxy aniline) Sn(II)silicate carbon nanotubes composite: Synthesis, characterization, structure-property relationships and applications

Anish Khan^{1, 2, †}, Aftab Aslam Parwaz Khan^{1, 2}, Abdullah M. Asiri^{1, 2}, Malik Abdul Rub^{1, 2}, Naved Azum^{1, 2}, Sher Bahadar Khan^{1, 2}, and Hadi M. Marwani^{1, 2}

¹Chemistry Department, King Abdulaziz University, Jeddah 21589, Saudi Arabia
²Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia

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A new class hybrid poly(2-methoxy aniline) Sn(II)silicate carbon nanotubes composite was synthesized by sol-gel method. The physico-chemical characterization was carried out by Scanning Electron micrograph, X-ray Diffraction, Fourier Transform Infrared, Ultraviolet-Visible Spectroscopy and simultaneous Thermo Gravimetric Analysis. The ion-exchange studies were also carried out to understand the ion-exchange capabilities. The dc electrical conductivity studies reviles its highly conducting nature in the range of 2-3^(-2) S cm-1. On the basis of distribution studies it was found highly selective for Hg2+. Due to selectivity of the composite, ion selective membrane was prepared and employed it as an indicator electrode in potentiometric titrations.

Keywords:Nanomaterials;Organic-inorganic hybrid;Cation-exchanger;Poly(o-methoxy aniline);Membrane;Electrode

[References]

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Kojma Y, Usuki A, Kawasumi M, Fukushima Y, Okada A, Kurayuchi T, Kamigaito O, J. Mater. Res., 8, 1185 (1993)
Liu JS, Tanaka T, Sivula K, Alivisatos AP, Frechet JMJ, J. Am. Chem. Soc., 126(21), 6550 (2004)
Gangopadhyay R, De A, Chem. Mater., 12, 608 (2000)
Tian ZQ, Lian YZ, Wang JQ, Wang SJ, Li WH, J. Electroanal. Chem., 308, 357 (1991)
Drelinkiewicz A, Hasik M, Kloc M, Catal. Lett., 64(1), 41 (2000)
Radford PT, Creager SE, Anal. Chim. Acta, 449, 199 (2001)
Bissessur R, White W, Mater. Chem. Phys., 99(2-3), 214 (2006)
Xu BH, Lin BZ, Sun DY, Ding C, Liu XZ, Xiao ZJ, Mater. Res. Bull., 42(9), 1633 (2007)
Murray RW, Molecular Design of Membrane Surfaces, Wiley, New York, 1992.
Finklea HO, Bard AJ, Rubinstein I, Electro Analytical Chemistry, Marcel Dekker, New York, 1996p. 19.
Grundig B, Wittstock G, Rudel U, Strehlitz B, J. Electroanal. Chem., 395(1-2), 143 (1995)
Ramesh P, Sampath SA, Anal. Chem., 72, 3369 (2000)
Zen JM, Senthil AK, Tsai DM, Electroanalysis, 15, 1073 (2003)
Sadakne M, Steckhan E, Chem. Rev., 98(1), 219 (1998)
Muller A, Kogerler P, Kuhlmann C, Chem. Commun., 15, 1347 (1999)
Lira-Cantu M, Gomez-Romero P, Chem. Mater., 10, 698 (1998)
Vaillant J, Lira-Cantu M, Cuentas-Gallegos K, Casan-Pastor N, Gomez-Romero P, Prog. Solid State Chem., 34, 147 (2006)
Heeger AJ, Synth. Met., 125, 23 (2002)

[Referenced By]

[1] Usuki A, Kojima M, Okada A, Fukushima Y, Kamigaito O, J. Mater. Res., 8, 1179 (1993)

[2] Kojma Y, Usuki A, Kawasumi M, Fukushima Y, Okada A, Kurayuchi T, Kamigaito O, J. Mater. Res., 8, 1185 (1993)

[3] Liu JS, Tanaka T, Sivula K, Alivisatos AP, Frechet JMJ, J. Am. Chem. Soc., 126(21), 6550 (2004)

[4] Gangopadhyay R, De A, Chem. Mater., 12, 608 (2000)

[5] Tian ZQ, Lian YZ, Wang JQ, Wang SJ, Li WH, J. Electroanal. Chem., 308, 357 (1991)

[6] Drelinkiewicz A, Hasik M, Kloc M, Catal. Lett., 64(1), 41 (2000)

[7] Radford PT, Creager SE, Anal. Chim. Acta, 449, 199 (2001)

[8] Bissessur R, White W, Mater. Chem. Phys., 99(2-3), 214 (2006)

[9] Xu BH, Lin BZ, Sun DY, Ding C, Liu XZ, Xiao ZJ, Mater. Res. Bull., 42(9), 1633 (2007)

[10] Murray RW, Molecular Design of Membrane Surfaces, Wiley, New York, 1992.

[11] Finklea HO, Bard AJ, Rubinstein I, Electro Analytical Chemistry, Marcel Dekker, New York, 1996p. 19.

[12] Grundig B, Wittstock G, Rudel U, Strehlitz B, J. Electroanal. Chem., 395(1-2), 143 (1995)

[13] Ramesh P, Sampath SA, Anal. Chem., 72, 3369 (2000)

[14] Zen JM, Senthil AK, Tsai DM, Electroanalysis, 15, 1073 (2003)

[15] Sadakne M, Steckhan E, Chem. Rev., 98(1), 219 (1998)

[16] Muller A, Kogerler P, Kuhlmann C, Chem. Commun., 15, 1347 (1999)

[17] Lira-Cantu M, Gomez-Romero P, Chem. Mater., 10, 698 (1998)

[18] Vaillant J, Lira-Cantu M, Cuentas-Gallegos K, Casan-Pastor N, Gomez-Romero P, Prog. Solid State Chem., 34, 147 (2006)

[19] Heeger AJ, Synth. Met., 125, 23 (2002)