Aqueous dispersions of iron oxide nanoparticles with linear-dendritic copolymers

Javad Safari; Zohre Zarnegar; Shabnam Farkhonde Masoule; Azade Enayati Najafabadi

Journal of Industrial and Engineering Chemistry, Vol.20, No.4, 2389-2393, July, 2014

DOI10.1016/j.jiec.2013.10.018 Export Citation

Aqueous dispersions of iron oxide nanoparticles with linear-dendritic copolymers

Javad Safari^†, Zohre Zarnegar, Shabnam Farkhonde Masoule, and Azade Enayati Najafabadi

Laboratory of Organic Compound Research, Department of Organic Chemistry, College of Chemistry, University of Kashan, P.O. Box 87317-51167, Kashan, Islamic Republic of Iran

E-mail:

In this study, we report an efficient synthetic method of water dispersible magnetite nanoparticles having oleic acid and poly(ethylene glycol)-poly(2-ethyl-2-oxazoline)-poly(ε-caprolactone) amphiphilic copolymer as magnetite nanoparticle dispersants. The Fe3O4 nanoparticles were prepared by chemical coprecipitation and had bilayer surface with hydrophobic inner poly(ε-caprolactone) layer and hydrophilic corona poly(ethylene glycol)-poly(2-ethyl-2-oxazoline) blocks. Moreover, role of time of ultrasonicating treatment, on percent of magnetite in the complex and its magnetic properties were investigated. Transmission electron microscopy (TEM) showed the average particle size of about 10-12 nm in diameter for nanoparticles.

Keywords:Fe3O4 nanoparticles;Ultrasound irradiation;Magnetic nanoparticles;Linear-dendritic copolymers;Poly(ε-caprolactone)

[References]

Wang Y, Morin G, Ona-Nguema G, et al., Environ. Sci. Technol., 45, 7258 (2011)
Sankaranarayanan V, Prakash O, Pant R, Islam M, J. Magn. Magn. Mater., 252, 7 (2002)
Williams JB, Ye Q, Hitchens TK, Kaufman CL, Ho C, J. Magn. Reson. Imaging, 25, 1210 (2007)
Asmatulu R, Zalich MA, Claus RO, Riffle JS, J. Magn. Magn. Mater., 292, 108 (2005)
Tan ST, Wendorff JH, Pietzonka C, Jia ZH, Wang GQ, Chem. Phys. Chem., 6, 1461 (2005)
Hu AG, Yee GT, Lin WB, J. Am. Chem. Soc., 127(36), 12486 (2005)
Roger J, Pons JN, Massart R, Halbreich A, Bacri JC, Eur. Phys. J. Appl. Phys., 5, 321 (1999)
Liberti PA, Rao CG, Terstappen LWMM, J. Magn. Magn. Mater., 225, 301 (2001)
Meerod S, Tumcharern G, Wichai U, Rutnakornpituk M, Polymer, 49(18), 3950 (2008)
Yuan JJ, Armes SP, Takabayashi Y, Prassides K, Leite CAP, Galembeck F, Lewis AL, Langmuir, 22(26), 10989 (2006)
Guardia P, Batlle-Brugal B, Roca AG, Iglesias O, Morales MP, Serna CJ, et al., J. Magn. Magn. Mater., 316, 756 (2007)
Avdeev MV, Bica D, Vekas L, Marinica O, Balasoiu M, Aksenov VL, et al., J. Magn. Magn. Mater., 311, 6 (2007)
Harris LA, Goff JD, Carmichael AY, Riffle JS, Harburn JJ, Pierre TGS, Saunders M, Chem. Mater., 15, 1367 (2003)
Zhang QA, Thompson MS, Carmichael-Baranauskas AY, Caba BL, Zalich MA, Lin YN, Mefford OT, Davis RM, Riffle JS, Langmuir, 23(13), 6927 (2007)
Jain TK, Morales MA, Sahoo SK, Leslie-Pelecky DL, Labhasetwar V, Mol. Pharmacol., 2(3), 194 (2005)
Naeini AT, Adeli M, Vossoughi M, Eur. Polym. J., 46, 165 (2010)
Didehban K, Namazi H, Entezami AA, Eur. Polym. J., 46, 1923 (2010)
Suek NW, Lamm MH, Langmuir, 24(7), 3030 (2008)
Adeli M, Zarnegar Z, J. Appl. Polym. Sci., 113(4), 2072 (2009)
Zhang XJ, Cheng JA, Wang QR, Zhong ZL, Zhuo RX, Macromolecules, 43(16), 6671 (2010)
Jiang G, Wang L, Chen W, Mater. Lett., 61, 278 (2007)
Cutler EC, Lundin E, Garabato BD, Choi D, Shon YS, Mater. Res. Bull., 42(6), 1178 (2007)
Mehdipoor E, Adeli M, Bavadi M, Sasanpourb P, Rashidian B, J. Mater. Chem., 21, 15456 (2011)
Safari J, Zarnegar Z, Heydarian M, Bull. Chem. Soc. Jpn., 85, 1332 (2012)
Namazi H, Adeli M, J. Polym. Sci. A: Polym. Chem., 43(1), 28 (2005)
Namazi H, Adeli M, Polymer, 46(24), 10788 (2005)
Feng C, Gu L, Yang D, Hu JH, Lu GL, Huang XY, Polymer, 50(16), 3990 (2009)

[Referenced By]

[1] Wang Y, Morin G, Ona-Nguema G, et al., Environ. Sci. Technol., 45, 7258 (2011)

[2] Sankaranarayanan V, Prakash O, Pant R, Islam M, J. Magn. Magn. Mater., 252, 7 (2002)

[3] Williams JB, Ye Q, Hitchens TK, Kaufman CL, Ho C, J. Magn. Reson. Imaging, 25, 1210 (2007)

[4] Asmatulu R, Zalich MA, Claus RO, Riffle JS, J. Magn. Magn. Mater., 292, 108 (2005)

[5] Tan ST, Wendorff JH, Pietzonka C, Jia ZH, Wang GQ, Chem. Phys. Chem., 6, 1461 (2005)

[6] Hu AG, Yee GT, Lin WB, J. Am. Chem. Soc., 127(36), 12486 (2005)

[7] Roger J, Pons JN, Massart R, Halbreich A, Bacri JC, Eur. Phys. J. Appl. Phys., 5, 321 (1999)

[8] Liberti PA, Rao CG, Terstappen LWMM, J. Magn. Magn. Mater., 225, 301 (2001)

[9] Meerod S, Tumcharern G, Wichai U, Rutnakornpituk M, Polymer, 49(18), 3950 (2008)

[10] Yuan JJ, Armes SP, Takabayashi Y, Prassides K, Leite CAP, Galembeck F, Lewis AL, Langmuir, 22(26), 10989 (2006)

[11] Guardia P, Batlle-Brugal B, Roca AG, Iglesias O, Morales MP, Serna CJ, et al., J. Magn. Magn. Mater., 316, 756 (2007)

[12] Avdeev MV, Bica D, Vekas L, Marinica O, Balasoiu M, Aksenov VL, et al., J. Magn. Magn. Mater., 311, 6 (2007)

[13] Harris LA, Goff JD, Carmichael AY, Riffle JS, Harburn JJ, Pierre TGS, Saunders M, Chem. Mater., 15, 1367 (2003)

[14] Zhang QA, Thompson MS, Carmichael-Baranauskas AY, Caba BL, Zalich MA, Lin YN, Mefford OT, Davis RM, Riffle JS, Langmuir, 23(13), 6927 (2007)

[15] Jain TK, Morales MA, Sahoo SK, Leslie-Pelecky DL, Labhasetwar V, Mol. Pharmacol., 2(3), 194 (2005)

[16] Naeini AT, Adeli M, Vossoughi M, Eur. Polym. J., 46, 165 (2010)

[17] Didehban K, Namazi H, Entezami AA, Eur. Polym. J., 46, 1923 (2010)

[18] Suek NW, Lamm MH, Langmuir, 24(7), 3030 (2008)

[19] Adeli M, Zarnegar Z, J. Appl. Polym. Sci., 113(4), 2072 (2009)

[20] Zhang XJ, Cheng JA, Wang QR, Zhong ZL, Zhuo RX, Macromolecules, 43(16), 6671 (2010)

[21] Jiang G, Wang L, Chen W, Mater. Lett., 61, 278 (2007)

[22] Cutler EC, Lundin E, Garabato BD, Choi D, Shon YS, Mater. Res. Bull., 42(6), 1178 (2007)

[23] Mehdipoor E, Adeli M, Bavadi M, Sasanpourb P, Rashidian B, J. Mater. Chem., 21, 15456 (2011)

[24] Safari J, Zarnegar Z, Heydarian M, Bull. Chem. Soc. Jpn., 85, 1332 (2012)

[25] Namazi H, Adeli M, J. Polym. Sci. A: Polym. Chem., 43(1), 28 (2005)

[26] Namazi H, Adeli M, Polymer, 46(24), 10788 (2005)

[27] Feng C, Gu L, Yang D, Hu JH, Lu GL, Huang XY, Polymer, 50(16), 3990 (2009)