Potentiometric determination of iron in polluted water samples using new modified Fe(III)-screen printed ion selective electrode

Tamer Awad Ali; Ahmed A. Farag; Gehad G. Mohamed

Journal of Industrial and Engineering Chemistry, Vol.20, No.4, 2394-2400, July, 2014

DOI10.1016/j.jiec.2013.10.019 Export Citation

Potentiometric determination of iron in polluted water samples using new modified Fe(III)-screen printed ion selective electrode

Tamer Awad Ali^†, Ahmed A. Farag, and Gehad G. Mohamed¹

Egyptian Petroleum Research Institute (EPRI), 11727 Cairo, Egypt
¹Chemistry Department, Faculty of Science, Cairo University, 12613 Giza, Egypt

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This article is focused on the determination of Fe(III) ion as an important factor in water pollution. A potentiometric method based on screen-printed ion-selective electrode was described for the determination of Fe(III) ion in different polluted water samples. It is based on incorporation of the Fe-phosphotungstate ion-associate in a screen-printed electrode (SPE) composition and tricresylpho-sphate (TCP) as plasticizer. The influences of the paste composition, different conditioning parameters and foreign ions on the electrode performance were investigated. The reversibility and also response time of the electrode have been studied. The electrode showed Nernstian response of 19.20 ± 0.73 mV decade-1 in the concentration range of 1 × 10^(-7)-2.5 × 10^(-2) mol L-1. The electrode was found to be usable within the pH range of 3-7.5 and exhibited a fast response time (about 7 s), low detection limit (1.57 × 10^(-7) mol L-1), long lifetime (>6 months) and good stability. The isothermal temperature coefficient (dE0/dt) of the electrode was calculated. The electrode was successfully applied for the determination of Fe(III) ion in pure solutions and polluted water samples (formation, tab and sea water samples) using potentiometric determination technique. The results obtained applying this potentiometric electrode is comparable with those obtained using inductive coupled plasma technique.

Keywords:Screen-printed sensors;Fe(III)-selective electrodes;Formation water;Water samples

[References]

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Gupta VK, Jain AK, Maheshwari G, Lang H, Ishtaiwi Z, Sens. Actuators B-Chem., 117, 99 (2006)
Segui MJ, Lizondo-Sabater J, Benito A, Martinez-Manez R, Pardo T, Sancenon F, Soto J, Talanta, 71, 333 (2007)
Mashhadizadeh MH, Shoaei IS, Monadi N, Talanta, 64, 1048 (2004)
Dasgupta PK, Huang H, Zhang G, Cobb GP, Talanta, 58, 153 (2002)
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Wilson D, Arada MD, Alegret S, del Valle M, J. Hazard. Mater., 181(1-3), 140 (2010)
Aghaie M, Giahi M, Aghaie H, Arvand M, Pournaghdy M, Yavari F, Desalination, 247(1-3), 346 (2009)
Kumar P, Shim YB, Talanta, 77, 1057 (2009)
Ali TA, Mohamed GG, El-Dessouky MM, Abou El Ella SM, Mohamed RTF, J. Sol. Chem., 42, 1336 (2013)
Authier L, Schollhorn B, Limoges B, Electroanalysis, 10, 1255 (1998)
Chernyshov DV, Khrenova MG, Pletnev IV, Shvedene NV, Mendeleev Commun., 18, 88 (2008)
Tymecki L, Zwierkowska E, Glab S, Koncki R, Sens. Actuators B-Chem., 96, 482 (2003)
Tymecki L, Jakubowska M, Achmatowicz S, Koncki R, Glab S, Anal. Lett., 34, 71 (2001)
Koncki R, Glab S, Dziwulska J, Palchetti I, Mascini M, Anal. Chim. Acta, 385, 451 (1999)
Khaled E, Mohamed GG, Awad T, Sens. Actuators B-Chem., 135, 74 (2008)
Ali TA, Mohamed GG, El-Dessouky MM, El Ella SMA, Mohamed RTF, Int. J. Electrochem. Sci., 8, 1469 (2013)
Mohamed GG, Ali TA, El-Shahat MF, Al-Sabagh AM, Migahed MA, Khaled E, Anal. Chim. Acta, 673, 79 (2010)
Frag EYZ, Ali TA, Mohamed GG, Awad YHH, Int. J. Electrochem. Sci., 7, 4443 (2012)
Mohamed GG, Ali TA, El-Shahat MF, Al-Sabagh AM, Migahed MA, Electroanalysis, 22, 2587 (2010)
Mohamed GG, El-Shahat MF, Al-Sabagh AM, Migahed MA, Ali TA, Analyst, 136, 1488 (2011)
Mohamed GG, Li TAA, El-Shahat MF, Migahed MA, Al-Sabagh AM, Drug Testing Anal., 4, 1009 (2012)
Singh AK, Mehtab S, Singh UP, Aggarwal V, Electroanalysis, 19, 1213 (2007)
Mahajan RK, Shaheen A, J. Colloid Interface Sci., 326(1), 191 (2008)
El-Dien FAN, Mohamed GG, Frag EYZ, Mohamed ME, Int. J. Electrochem. Sci., 7, 10266 (2012)
Buck RP, Lindner E, Pure Appl. Chem., 66, 2527 (1994)
Matesic-Puac R, Sak-Bosnar M, Bilic M, Grabaric BS, Sens. Actuators B-Chem., 106, 221 (2005)
Sa’ez de Viteri FJ, Diamond D, Analyst, 119, 749 (1994)
Boudouh H, Essehli R, Guessasma S, Aissat A, Mater. Chem. Phys., 133(1), 383 (2012)
Gupta VK, Jain AK, Agarwal S, Maheshwari G, Talanta, 71, 1964 (2007)
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Sil A, Ijeri VS, Srivastava AK, Sens. Actuators B-Chem., 106, 648 (2005)
Bralic M, Brinic S, Generalic E, Vrsalovic L, Talanta, 63, 777 (2004)
Motlagh MG, Taher MA, Ahmadi A, Electrochim. Acta, 55(22), 6724 (2010)
Bralic M, Radic N, Analusis, 27, 57 (1999)
Zamani HA, Ganjali MR, Faridbod F, Salavati-Niasari M, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 32, 564 (2012)

[Referenced By]

[1] Masrournia M, Zamani HA, Mirrashid HA, Ganjali MR, Faridbod F, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 31, 574 (2011)

[2] Bhat VS, Ijeri VS, Srivastava AK, Sens. Actuators B-Chem., 99, 98 (2004)

[3] Gupta VK, Jain AK, Maheshwari G, Lang H, Ishtaiwi Z, Sens. Actuators B-Chem., 117, 99 (2006)

[4] Segui MJ, Lizondo-Sabater J, Benito A, Martinez-Manez R, Pardo T, Sancenon F, Soto J, Talanta, 71, 333 (2007)

[5] Mashhadizadeh MH, Shoaei IS, Monadi N, Talanta, 64, 1048 (2004)

[6] Dasgupta PK, Huang H, Zhang G, Cobb GP, Talanta, 58, 153 (2002)

[7] Teixeira MFDS, Aniceto C, Fatibello-Filho O, J. Braz. Chem. Soc., 9, 506 (1998)

[8] Wilson D, Arada MD, Alegret S, del Valle M, J. Hazard. Mater., 181(1-3), 140 (2010)

[9] Aghaie M, Giahi M, Aghaie H, Arvand M, Pournaghdy M, Yavari F, Desalination, 247(1-3), 346 (2009)

[10] Kumar P, Shim YB, Talanta, 77, 1057 (2009)

[11] Ali TA, Mohamed GG, El-Dessouky MM, Abou El Ella SM, Mohamed RTF, J. Sol. Chem., 42, 1336 (2013)

[12] Authier L, Schollhorn B, Limoges B, Electroanalysis, 10, 1255 (1998)

[13] Chernyshov DV, Khrenova MG, Pletnev IV, Shvedene NV, Mendeleev Commun., 18, 88 (2008)

[14] Tymecki L, Zwierkowska E, Glab S, Koncki R, Sens. Actuators B-Chem., 96, 482 (2003)

[15] Tymecki L, Jakubowska M, Achmatowicz S, Koncki R, Glab S, Anal. Lett., 34, 71 (2001)

[16] Koncki R, Glab S, Dziwulska J, Palchetti I, Mascini M, Anal. Chim. Acta, 385, 451 (1999)

[17] Khaled E, Mohamed GG, Awad T, Sens. Actuators B-Chem., 135, 74 (2008)

[18] Ali TA, Mohamed GG, El-Dessouky MM, El Ella SMA, Mohamed RTF, Int. J. Electrochem. Sci., 8, 1469 (2013)

[19] Mohamed GG, Ali TA, El-Shahat MF, Al-Sabagh AM, Migahed MA, Khaled E, Anal. Chim. Acta, 673, 79 (2010)

[20] Frag EYZ, Ali TA, Mohamed GG, Awad YHH, Int. J. Electrochem. Sci., 7, 4443 (2012)

[21] Mohamed GG, Ali TA, El-Shahat MF, Al-Sabagh AM, Migahed MA, Electroanalysis, 22, 2587 (2010)

[22] Mohamed GG, El-Shahat MF, Al-Sabagh AM, Migahed MA, Ali TA, Analyst, 136, 1488 (2011)

[23] Mohamed GG, Li TAA, El-Shahat MF, Migahed MA, Al-Sabagh AM, Drug Testing Anal., 4, 1009 (2012)

[24] Singh AK, Mehtab S, Singh UP, Aggarwal V, Electroanalysis, 19, 1213 (2007)

[25] Mahajan RK, Shaheen A, J. Colloid Interface Sci., 326(1), 191 (2008)

[26] El-Dien FAN, Mohamed GG, Frag EYZ, Mohamed ME, Int. J. Electrochem. Sci., 7, 10266 (2012)

[27] Buck RP, Lindner E, Pure Appl. Chem., 66, 2527 (1994)

[28] Matesic-Puac R, Sak-Bosnar M, Bilic M, Grabaric BS, Sens. Actuators B-Chem., 106, 221 (2005)

[29] Sa’ez de Viteri FJ, Diamond D, Analyst, 119, 749 (1994)

[30] Boudouh H, Essehli R, Guessasma S, Aissat A, Mater. Chem. Phys., 133(1), 383 (2012)

[31] Gupta VK, Jain AK, Agarwal S, Maheshwari G, Talanta, 71, 1964 (2007)

[32] Ekmekci G, Uzun D, Somer G, Kalayci S, J. Membr. Sci., 288(1-2), 36 (2007)

[33] Sil A, Ijeri VS, Srivastava AK, Sens. Actuators B-Chem., 106, 648 (2005)

[34] Bralic M, Brinic S, Generalic E, Vrsalovic L, Talanta, 63, 777 (2004)

[35] Motlagh MG, Taher MA, Ahmadi A, Electrochim. Acta, 55(22), 6724 (2010)

[36] Bralic M, Radic N, Analusis, 27, 57 (1999)

[37] Zamani HA, Ganjali MR, Faridbod F, Salavati-Niasari M, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 32, 564 (2012)