Sulfonation of a hypercrosslinked polymer adsorbent for microwave-assisted desorption of adsorbed benzene

Qing Bo Meng; Go-Su Yang; Youn-Sik Lee

Journal of Industrial and Engineering Chemistry, Vol.20, No.4, 2484-2489, July, 2014

DOI10.1016/j.jiec.2013.10.030 Export Citation

Sulfonation of a hypercrosslinked polymer adsorbent for microwave-assisted desorption of adsorbed benzene

Qing Bo Meng, Go-Su Yang¹, and Youn-Sik Lee^†

Division of Chemical Engineering, Nanomaterials Processing Research Center, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do 561-756, Republic of Korea
¹Department of Environmental Engineering, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do 561-756, Republic of Korea

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Optipore V503, a commercial hypercrosslinked hydrophobic polymer adsorbent, was sulfonated to become hydrophilic to allow more efficient microwave-assisted desorption of adsorbed nonpolar volatile organic compounds (VOCs) such as benzene under humidified conditions. Compared to Optipore V503, the hydrophilic adsorbents showed reduced adsorption capacities towards benzene, but significantly improved microwave-assisted desorption efficiencies under a semi-continuous 600 W microwave irradiation process. The increased desorption efficiency was mainly attributed to adsorbed water, which indirectly allowed heating of the polymer adsorbents to higher temperatures upon irradiation by microwaves.

Keywords:Hypercrosslinked polymer adsorbent;Sulfonation;Adsorption;Nonpolar VOC;Microwave-assisted desorption

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Li B, Su F, Luo HK, Liang L, Tan B, Microporous Mesoporous Mater., 135, 214 (2011)
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[2] Opperman SH, Brown RC, Pollut. Eng., 31, 60 (1999)

[3] Di P, Chang DPY, Microwave Regeneration of Volatile Organic Compound (VOC) Adsorbents, in: Air & Waste Management Association 89th Annual Meeting and Exhibition, Nashville, 1996.

[4] Price DW, Schmidt PS, J. Air. Waste. Manage. Assoc., 48, 1145 (1998)

[5] Reub J, Bathen D, Schmidt-Traub H, Chem. Eng. Technol., 25, 384 (2002)

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[7] Hashisho Z, Rood M, Botich L, Environ. Sci. Technol., 39, 6859 (2005)

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[10] Cherbanski R, Komorowska-Durka M, Stefanidis GD, Stankiewicz AI, Ind. Eng. Chem. Res., 50, 8644 (2011)

[11] Long C, Li Y, Yu W, Li A, J. Hazard. Mater., 203-204, 256 (2012)

[12] Okay O, Prog. Polym. Sci., 25, 779 (2000)

[13] Erdmenger T, Becer CR, Hoogenboom R, Schubert US, Aust. J. Chem., 62, 63 (2009)

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