화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.4, 2603-2609, July, 2014
DOI10.1016/j.jiec.2013.10.047  Export Citation
Sorption kinetics of sulphate ions on quaternary ammonium-modified rice straw
Wei Cao1, Zhi Dang2, 3, †, Bao-Ling Yuan1, Chun-Hua Shen1, Jin Kan1, and Xiu-Ling Xue4
  • 1College of Civil Engineering, Huaqiao University, Xiamen 361021, PR China
  • 2School of Environment and Energy, South China University of Technology, Guangzhou 510006, PR China
  • 3Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, Guangzhou 510006, PR China
  • 4College of Chemical Engineering, Huaqiao University, Xiamen 361021, PR China
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Batch sorption experiments with variable concentration of sulphate and temperature were conducted to investigate sorption kinetics of sulphate ions on quaternary ammonium-modified rice straw (QMRS). Kinetic data were discussed with pseudo first- and second-order rate equations and diffusion models. The results showed the sorption equilibrium time is about 20 min and the activated energy Ea is 19.3 kJ/mol. Increase of temperature and initial sulphate concentration favored sorption process. The sorption kinetics followed pseudo second-order rate equation, and the overall rate was determined by film diffusion. Additionally, characterization by 13C NMR and EDS confirmed the presence of quaternary ammonium groups in QMRS.
Keywords:Sulphate ions;Sorption kinetics;Quaternary ammonium modification;Rice straw;Sorption activated energy
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