Journal of Chemical Physics, Vol.101, No.2, 1725-1729, 1994
Spectral Quantization of Transition-State Dynamics for the 3-Dimensional H+h2 Reaction
Applying a spectral quantization method, we find the positions and widths of 32 transition state resonances in the three-dimensional reaction H+H-2 with J=0. The assignment of many of the resonances appears to follow asymmetric stretch and bend progressions for a linear triatomic molecule.
Keywords:SCHRODINGER-EQUATION;ROTATIONAL SPECTRUM;CHEMICAL-REACTIONS;QUANTUM-MECHANICS;GEOMETRIC PHASE;RESONANCES;SCATTERING;H-3;COLLISIONS;PROBABILITIES