The surface chemistry of NH3 decomposition and oxidation was examined over Mn+/Cen+/Na+/gamma-Al2O3 commercial catalysts incorporating Pt, Pd, and Rh in order to clarify the role of these materials in converting NH3 into N-2 and NOx within the dense phase of FCC regenerators. All catalysts were active in promoting the decomposition of NH3 into N-2 in the 500-700 degrees C temperature range, with the Rh containing catalyst being the most active at 700 degrees C. Oxygen species activated on the surfaces of these materials significantly enhanced the selective conversion of NH3 into N-2. When O-2 was present in the feed, complete conversion of NH3 - with approximately 80% selectivity to N-2 - was observed over the reduced Pt-, Pd-, and Rh-containing materials at temperatures as low as 200, 300, and 350 degrees C, respectively. At temperatures below 350 degrees C, the NH3 oxidation reaction follows an iSCR-type pathway, in which a fraction of NH3 is converted into NOx and subsequently into surface nitrite/nitrate species capable of reacting with the remaining portion of NH3 to form N-2. Although the oxidation of NH3 to NOx prevails at 700 degrees C under excess O-2 conditions, optimal O-2 concentrations can be found under which both complete NH3 conversion and high N-2 selectivity are achieved. Under these conditions, the noble metal component of the Mn+/Cen+/Na+/gamma-Al2O3 materials promotes the reaction of NH3 with the NOx formed, yielding N-2. Excess O-2 effectively hinders this reaction pathway at high temperatures. Overall, the results presented herein indicate that the significant increase in NOx emissions, typically observed over conventional Pt-based FCC CO combustion promoters, could be directly attributed to the oxidation of NH3 formed in the reducing zone of the FCC regenerators. (c) 2012 Elsevier B.V. All rights reserved.