Journal of Chemical Physics, Vol.101, No.5, 4083-4092, 1994
Frequency-Spectra for Fluids Beyond the Mean Spherical Approximation
In this paper, we investigate the frequency spectra of fluids (or fluid-like disordered materials) composed of particles with embedded harmonic oscillators. The general treatment is particularized at the low density limit, and a working scheme to add corrections to the mean spherical approximation for arbitrary density is introduced. A detailed comparison with an exactly solvable model in one dimension is also presented.
Keywords:TOPOLOGICALLY DISORDERED SYSTEM;TIGHT-BINDING MODEL;POLARIZABLE FLUIDS;REFRACTIVE-INDEX;BAND-STRUCTURE;LIQUIDS;STATES;DENSITY;SIMULATION