Journal of Chemical Physics, Vol.101, No.5, 4407-4417, 1994
Coupling Between Diffusion and Deformation of Gels in Binary Solvents - A Model Study
We study theoretically the dynamics of chemically crosslinked gels in binary solvents on the basis of the Flory-type model and nonequilibrium thermodynamics. We find with the aid of numerical integration of the evolution equation that an instability occurs in the gel upon changing the composition of the surrounding solution. This instability is caused by a marked difference of timescales between quick mutual diffusion of solvent molecules and slow deformation of the gel network. Profiles of solvent composition and network deformation are also described in some details.
Keywords:VOLUME PHASE-TRANSITION;N-ISOPROPYLACRYLAMIDE GELS;POLYMER-SOLUTIONS;KINETICS;MIXTURES;NETWORKS;MEDIA