고분자 알로이용 고효율 상용화제의 개발에 관한 연구

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Journal of the Korean Industrial and Engineering Chemistry, Vol.7, No.4, 757-767, August, 1996

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고분자 알로이용 고효율 상용화제의 개발에 관한 연구

Study on the Development of Highly Efficient Compatibilizer for Polymer Alloys

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초록

폴리(알킬아크릴레이트-g-카프로락톤) 그라프트 공중합체를 합성하였으며, 이것을 폴리카보네이트(PC)/폴리(아크릴로니트릴-부타디엔-스티렌)(ABS) 블렌드의 상용화제로 사용하였다. PC나 ABS와 비상용성인 폴리 알킬아크릴 레이트 주사슬을 갖는 그라프트 공중합체를 사용하였으며 이것을 PC/ABS의 계면에 위치시키는 것을 목표로 하였다. 그라프트 공중합체를 1중량부 포함하는 블렌드물은 충격 강도는 물론 파단 인장 강도에서 아주 향상된 값을 보였으며, 1/8인치 시편에서의 충격 강도 향상이 두드러졌다. 전자현미경에 의한 형태학적인 분석 결과 그라프트 공중합체의 존재가 좀더 매끄러운 PC/ABS 계면을 형성하게 하는 것으로 나타났다.

Poly(alkyl acrylate-g-caprolactone) graft copolymers were prepared, and they were applied as compatibilizing agents for polycarbonate (PC) / poly(acrylonitrile-butadiene-styrene) (ABS) blends. The incompatible poly(alkyl acrylate) segment was incorporated into the graft copolymer in order to localize the copolymer at the PC/ABS interface. The blend containing 1 phr of the copolymer showed remarkable improvements in impact strength as well as in elongation at break. Impact improvement was more pronounced with a thinner test specimens of 1/8 inch thickness. Morphological study showed that the presence of the graft copolymer led to a smoother PC/ABS interface due to the interfacial enrichment of the graft copolymer.

[References]

Paul DR, "Polymer Blends," Academic Press, New York (1978)
Utracki LA, "Polymer Alloys and Blends," Hansa Publishers, Munich (1990)
Folkes MJ, Hope RS, "Polymer Blends and Alloys," Chapman & Hall, Cambridge (1993)
Leibler L, Makromol. Chem. Makromol. Symp., 16, 1 (1988)
Noolandi J, Hong KM, Macromolecules, 15, 482 (1982)
Noolandi J, Hong KM, Macromolecules, 17, 1531 (1984)
Dai KH, Kramer EJ, Shull KR, Macromolecules, 25, 220 (1992)
Thomas S, Prudhomme RE, Polymer, 33, 4260 (1992)
Brown HR, Macromolecules, 22, 2859 (1989)
Auschra C, Stadler R, Macromolecules, 26, 6364 (1993)
Jerome DR, Teyssie P, Macromolecules, 24, 977 (1991)
Dong L, Greco R, Orsello G, Polymer, 34, 1375 (1993)
Brandrup J, Immergut EH, "Polymer Handbook," 3rd ed., Chap. 6, John Wiley & Sons, New York (1989)
Eastmond GC, Ming JM, Malinconico M, Br. Polym. J., 19, 275 (1987)
Sakellariou P, Eastmond GC, Miles IS, Polymer, 32, 2351 (1991)
Sakellariou P, Eastmond GC, Miles IS, Polymer, 33, 4493 (1992)
Suh KS, Lee DS, Kang CG, Polym.(Korea), 19(2), 254 (1995)
Surez H, Barlow JW, Paul DR, J. Appl. Polym. Sci., 29, 3253 (1984)
Chiang WY, Hwung DS, Polym. Eng. Sci., 27, 632 (1987)
Mark H, "Encyclopedia of Polymer Science and Engineering," 2nd ed., Vol. 11, 648-718, John Wiley & Sons, New York (1988)

[Referenced By]

[1] Paul DR, "Polymer Blends," Academic Press, New York (1978)

[2] Utracki LA, "Polymer Alloys and Blends," Hansa Publishers, Munich (1990)

[3] Folkes MJ, Hope RS, "Polymer Blends and Alloys," Chapman & Hall, Cambridge (1993)

[4] Leibler L, Makromol. Chem. Makromol. Symp., 16, 1 (1988)

[5] Noolandi J, Hong KM, Macromolecules, 15, 482 (1982)

[6] Noolandi J, Hong KM, Macromolecules, 17, 1531 (1984)

[7] Dai KH, Kramer EJ, Shull KR, Macromolecules, 25, 220 (1992)

[8] Thomas S, Prudhomme RE, Polymer, 33, 4260 (1992)

[9] Brown HR, Macromolecules, 22, 2859 (1989)

[10] Auschra C, Stadler R, Macromolecules, 26, 6364 (1993)

[11] Jerome DR, Teyssie P, Macromolecules, 24, 977 (1991)

[12] Dong L, Greco R, Orsello G, Polymer, 34, 1375 (1993)

[13] Brandrup J, Immergut EH, "Polymer Handbook," 3rd ed., Chap. 6, John Wiley & Sons, New York (1989)

[14] Eastmond GC, Ming JM, Malinconico M, Br. Polym. J., 19, 275 (1987)

[15] Sakellariou P, Eastmond GC, Miles IS, Polymer, 32, 2351 (1991)

[16] Sakellariou P, Eastmond GC, Miles IS, Polymer, 33, 4493 (1992)

[17] Suh KS, Lee DS, Kang CG, Polym.(Korea), 19(2), 254 (1995)

[18] Surez H, Barlow JW, Paul DR, J. Appl. Polym. Sci., 29, 3253 (1984)

[19] Chiang WY, Hwung DS, Polym. Eng. Sci., 27, 632 (1987)

[20] Mark H, "Encyclopedia of Polymer Science and Engineering," 2nd ed., Vol. 11, 648-718, John Wiley & Sons, New York (1988)