Applied Surface Science, Vol.297, 125-129, 2014
The electrical properties of low pressure chemical vapor deposition Ga doped ZnO thin films depending on chemical bonding configuration
The electrical and chemical properties of low pressure chemical vapor deposition (LP-CVD) Ga doped ZnO (ZnO: Ga) films were systematically investigated using Hall measurement and X-ray photoemission spectroscopy (XPS). Diethylzinc (DEZ) and O-2 gas were used as precursor and reactant gas, respectively, and trimethyl gallium (TMGa) was used as a Ga doping source. Initially, the electrical properties of undoped LP-CVD ZnO films depending on the partial pressure of DEZ and O-2 ratio were investigated using Xray diffraction (XRD) by changing partial pressure of DEZ from 40 to 140 mTorr and that of O-2 from 40 to 80 mTorr. The resistivity was reduced by Ga doping from 7.24 x 10(-3) Omega cm for undoped ZnO to 2.05 x 10(-3) Omega cm for Ga doped ZnO at the TMG pressure of 8 mTorr. The change of electric properties of Ga doped ZnO with varying the amount of Ga dopants was systematically discussed based on the structural crystallinity and chemical bonding configuration, analyzed by XRD and XPS, respectively. (C) 2014 Elsevier B.V. All rights reserved.