The properties of selection of photocatalytic monolithic materials were briefly reviewed and in test phase alveolar open-cell self-bonded beta-SiC foams with medium surface and 4500 mu m mean cell size were employed to immobilize sol-gel and commercial-grade TiO2 and thus to structure flow-through photoreactors that would be effective in water and air detoxification. TiO2/beta-SiC foam monoliths were characterized in terms of their morphology, pressure drop, light transmission ability, static mixer role and photocatalytic activity under UV-A. When operated in a recirculation mode, repetitive reaction cycles occurred successfully without any decrease in activity in Diuron degradation. Foams also proved efficient when used in the single-pass degradation of gaseous methylethylketone. (C) 2013 Elsevier B.V. All rights reserved.