화학공학소재연구정보센터
International Journal of Energy Research, Vol.38, No.4, 518-523, 2014
Electrochemical study of nanostructured electrode for low-temperature solid oxide fuel cell (LTSOFC)
Zn-based nanostructured Ba0.05Cu0.25Fe0.10Zn0.60O (BCFZ) oxide electrode material was synthesized by solid-state reaction for low-temperature solid oxide fuel cell. The cell was fabricated by sandwiching NK-CDC electrolyte between BCFZ electrodes by dry press technique, and its performance was assessed. The maximum power density of 741.87 mW-cm(-2) was achieved at 550 degrees C. The crystal structure and morphology were characterized by X-ray diffractometer (XRD) and SEM. The particle size was calculated to be 25 nm applying Scherer's formula from XRD data. Electronic conductivities were measured with the four-probe DC method under hydrogen and air atmosphere. AC Electrochemical Impedance Spectroscopy of the BCFZ oxide electrode was also measured in hydrogen atmosphere at 450 degrees C. Copyright (c) 2013 John Wiley & Sons, Ltd.