This work investigated the effect of the oxygen enrichment in the intake air of diesel engines on the combustion and emissions performance using rape seed oil (RSO) as a fuel. The purpose of the paper is to investigate the potential of oxygen enrichment in the intake air method to restrain the deterioration of particulate emissions of the RSO due to its high viscosity so as to explore the possibility of direct use of SVO (straight vegetable oil) in diesel engines, which can reduce CO2 emissions and save cost. The combustion parameters such as ignition delay, heat release rate, in-cylinder peak temperature and pressure were determined. Engine out particulate and gaseous emissions of the RSO were measured at oxygen concentrations from 21% (by volume) (no enrichment) to 24% (by volume) and compared to diesel results. The enrichment of the intake air with oxygen decreased the ignition delay and premixed combustion duration, and increased the in-cylinder peak pressure and temperature. The particulate, CO and hydrocarbon emissions were significantly reduced while the NOx emissions increased as the oxygen enrichment rate increased. 22% oxygen enrichment rate was suggested to achieve lower than diesel particulate emissions with the lowest NOx penalty. Increased NOx could be controlled by other methods. The results show that the oxygen enrichment in intake air method enabled direct combustion of SVO in diesel engines with reduced particulate, hydrocarbon and CO emissions. (C) 2013 Elsevier Ltd. All rights reserved.