Three Kraft lignins isolated from black liquors of several paper pulp mills of the North of Spain and Portugal were structurally characterized by using monodimensional (H-1 and C-13) and bidimensional Nuclear Magnetic Resonance (NMR) spectrometry. From the latter, C-13-H-1 heteronuclear single quantum correlation (HSQC) and heteronuclear multiple bond correlation (HMBC) were employed. Lignins from black liquors are usually burned for power generation. Nevertheless, they could become high value added products within a biorefinery context. In that case, a good understanding of their structure is a prior step to transform them. From all the NMR techniques studied, HSQC has risen as the most powerful tool in lignin characterization. Kraft cooking conditions and the type of wood seem to be the main factors that determine the differences observed in the lignins. All the samples have shown an important decrease in the number of beta-O-4 ' linkages, due to the Kraft process, and resinol has become the most resistant linkage to the process. Moreover, all samples seem to be mainly linked to a one polysaccharide: xylan. Several parameters like S/G ratio, portion of phenolic and aliphatic hydroxyls, amount of aromatic protons and other structural aspects were also estimated. (C) 2014 Elsevier Ltd. All rights reserved.