A softwood Kraft black liquor was acidified with carbon dioxide at 115 degrees C and 6.2 bar over a pH range of 13.6-9.5, resulting in the precipitation of liquefied-lignin fractions as a separate phase. Seven such "liquid-lignin" fractions were produced, with each fraction being phase-separated within a narrow pH band of 0.5 units. The fractions were found to be highly hydrated phases, containing 32.3-48.2 wt.% water; as a result, their measured melting points were quite low, 90.7-110.5 degrees C. In contrast, no melting point was detected up to 375 degrees C for any of the lignin fractions after drying. Significant reductions in metals content were observed for the lignin fractions compared to the original black-liquor feed. (C) 2013 Elsevier Ltd. All rights reserved.