An advanced aqueous amine solvent of tetramethylammonium glycinate ([N-1111][Gly]) was characterized for carbon dioxide (CO2) absorption purposes. Density, viscosity and pH of the [N-1111][Gly] solution, with concentrations ranging from 5% to 30%, were determined at temperatures from 298 to 323 K. Solubility and diffusivity of CO2 in [N-1111][Gly] solution at the same temperatures and concentrations was estimated. Absorption of CO2 into [N-1111][Gly] aqueous solution was investigated using a double stirred-cell absorber with a planar gas-liquid interface. The effects of the [N-1111][Gly] concentration, temperature and CO2 concentration of absorption CO2 into aqueous [N-1111][Gly] were studied. The kinetics study showed that absorption CO2 into aqueous [N-1111][Gly] was the fast pseudo-first order reaction regime. Based on the reaction regime, the enhancement factor E, the overall reaction kinetic constant k(ov) and the second-order rate constant k(2) were obtained using the two-film model. The results showed that E was linear with C-B0(1/2), and the activation energy of 15% aqueous [N-1111][Gly] absorbing CO2 was 15.431 kJ mol(-1). (C) 2011 Elsevier B.V. All rights reserved.