화학공학소재연구정보센터
Journal of Chemical Physics, Vol.103, No.16, 6959-6965, 1995
Binary Diffusion-Coefficients of Helium/Hydrogen Isotope Mixtures
Mass diffusion coefficients have been measured for the six binary mixtures formed from He-3 and He-4 with hydrogen, deuterium, and tritium. An intermolecular potential of the Hartree-Fock-dispersion form is presented which, when employed in the quantum mechanical theoretical evaluation of the diffusion coefficient, correlates experimental results for all six systems within the experimental uncertainty. No isotopic effect is displayed by the correlating potential.