TiO2 coated gamma-Al2O3 prepared by sol-gel method (SG/gamma-Al2O3) were filled in a dielectric barrier discharge (DBD) reactor to remove styrene which is a typical VOC with high toxicity and odorous smell. Compared with traditional commercial P25 TiO2 powder coated gamma-Al2O3 (P25/gamma-Al2O3), TiO2 loading quantity could be controlled with different coating times by sol-gel method. However for P25/gamma-Al2O3, the loading quantity was difficult to be increased because P25 would easily fall off when the coating film got thicker. The calcination temperature and coating times were optimized in this research. The results showed that the SG/gamma-Al2O3 calcined at 550 degrees C owned the best catalytic activity and the carbon deposition on catalyst surface could be efficiently reduced with increase of TiO2 loading quantity, while large amount of carbon deposition was observed on P25/gamma-Al2O3. Meanwhile O-3 decrease efficiency also improved from 18% with P25/gamma-Al2O3 to 36% with SG/gamma-Al2O3 and less O-3 was detected in outlet gas. Other factors like specific input energy (SIE) and oxygen content were also investigated and optimized. When the applied voltage was 12.5 kV, 100% O-2 flowed, the selectivity of CO and CO2 could reach 100% and nearly no carbon deposition could be observed on TiO2 surface. Additionally, the formation of by-products, including NOx, in the reaction system and the plausible reaction mechanism of DBD combined with TiO2 catalyst were also detected and discussed. (C) 2013 Published by Elsevier B.V.