Chemical Engineering Journal, Vol.244, 234-242, 2014
Experimental study of heat transport in catalytic sponge packings by monitoring spatial temperature profiles in a cooled-wall reactor
The heat transport characteristics of catalytically coated sponge packings and of a packed bed of spherical shell-catalysts were investigated by performing the exothermal hydrogenation of benzene in a tubular reactor with cooled wall. Temperatures inside the catalyst beds were monitored at up to 108 different positions. Steady-state temperature distributions in the catalyst beds were used to elucidate effects of support type and, in case of sponges, of pore density, porosity and thermal conductivity coefficient on heat transfer. Smoothed temperature profiles and reduced hot spot temperatures at equal operation conditions and, in particular, at states of equal over-all heat production by reaction are indicative of enhanced heat transport to the cooled reactor wall. The results show that sponge packings exhibit better heat transfer properties than packed beds of particles. When sponge supports are compared among each other, the thermal conductivity coefficient of the solid material was found to have the strongest impact on heat transfer. (C) 2014 Elsevier B.V. All rights reserved.
Keywords:Sponges;Open-cell foams;Packed bed of particles;Catalyst supports;Effective two-phase thermal conductivity;Benzene hydrogenation