화학공학소재연구정보센터
Journal of Chemical Physics, Vol.103, No.23, 10050-10057, 1995
Monomer-Excimer Kinetics in Solution .3. Generalized Smoluchowski Approach
A generalized Smoluchowski approach developed in A. Molski, Chem. Phys. 182, 203 (1994) is employed to study reversible excimer formation in solution. For contact excimer formation, relations among the rate coefficients are analyzed for three modes of excitation; initially pulsed, steady-state, and periodic. A new kinetic Laplace transform relation for the frequency domain is demonstrated in the linear harmonic regime. The Laplace transform relations between the time domain and steady states, derived in W. Naumann and A. Molski, J. Chem. Phys. 100, 1511, 1520 (1994) for interaction-free models, are shown to be also valid when the interaction forces are included.