The first three-dimensional potential energy surface (PES) of the Kr-OCS complex is developed at the CCSD(T) level with a large basis set plus midpoint bond functions. The potential includes explicit dependence on the v(3) antisymmetric stretching coordinate of the OCS molecule. Two vibrationally adiabatic potentials with the OCS molecule at both the ground and the first vibrational v(3) excited states are generated. The resulting potentials provide a good representation of the experimental infrared data: for 66 infrared transitions the root-mean-square discrepancy is about 0.011 cm(-1). The calculated infrared band origin shift, bending ground frequency, and molecular constants associated with the v(3) fundamental of OCS are all in better agreement with the experimental counterparts. (c) 2012 Elsevier B.V. All rights reserved.