We theoretically investigated the ultrafast dynamics of high-contrast nano-grating formation on gold film surface with respect to non-equilibrium thermal excitation processes. It is proposed that the high-contrast nano-grating can be desirably achieved by optimizing the non-equilibrium thermal dynamics processes. The grating contrast can be largely promoted by 64% with adjusting thermal dynamics via tailoring temporally shaped femtosecond laser. The results are attributed to the competitive energy transfer routes between electrons thermal diffusion and electron-phonon relaxation processes during grating formation, which can be well manipulated by temporally shaped femtosecond laser. The study provides for strategy for production of high-quality periodic surface structures with sharp grating profiles. (C) 2014 Elsevier B.V. All rights reserved.